Soluble non-toxic carbon nano-rods for the selective sensing of iron(iii) and chromium(vi)

N. Chauhan, S.R. Anand, R. Aggarwal, J. Kaushik, S.S. Shekhawat, A.K. Sonker (Corresponding Author), S.K. Sonkar (Corresponding Author)

Research output: Contribution to journalArticleScientificpeer-review

12 Citations (Scopus)

Abstract

Herein, we report a simpler functionalization of the CNR by the amine (2,2′-(ethylenedioxy)-bis(ethylamine)) (H 2NCH 2CH 2OCH 2CH 2OCH 2CH 2NH 2 (EDA)) molecules as a surface passivating agent to achieve soluble functionalized carbon nano-rods (f-CNR). The surface-functionalized fluorescent f-CNR exhibited the quantum yield value of ∼16% and were used as a fluorescent probe for the selective detection of the Cr(vi) and Fe(iii) ions in a homogeneous aqueous phase based on fluorescence quenching. In particular, the limits of the detection for both metal ions were obtained to be ∼43 nM for Fe(iii) and ∼11 nM for Cr(vi), which were quite significant in aqueous media. Moreover, the f-CNR showed non-toxicity and was biocompatible with Escherichia coli (E. coli) (ATCC 25922) cells when tested up to 9 mg mL -1.

Original languageEnglish
Pages (from-to)10726-10734
JournalNew Journal of Chemistry
Volume43
Issue number27
DOIs
Publication statusPublished - 2019
MoE publication typeA1 Journal article-refereed

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