Stable glycosylamines at the reducing ends of cellulose nanocrystals

Jingwen Xia; Tetyana Koso; Katja Heise; Lukas Fliri; Emilie Ressouche; Johanna Majoinen; Mauri A. Kostiainen; Sami Hietala; Michael Hummel; Vladimir Aseyev; Ilkka Kilpeläinen; Alistair W.T. King

doi:10.1039/D3CC01329D

Stable glycosylamines at the reducing ends of cellulose nanocrystals

Jingwen Xia, Tetyana Koso, Katja Heise, Lukas Fliri, Emilie Ressouche, Johanna Majoinen, Mauri A. Kostiainen, Sami Hietala, Michael Hummel, Vladimir Aseyev^*, Ilkka Kilpeläinen^*, Alistair W.T. King^*

^*Corresponding author for this work

BA5407 Bioinspired materials

Research output: Contribution to journal › Article › Scientific › peer-review

5 Citations (Scopus)

Abstract

The reaction of reducing end groups in cellulose nanocrystals with dodecylamine was examined. Using a direct-dissolution solution-state NMR protocol, the regioselective formation of glucosylamines was shown. This provides an elegant approach to sustainably functionalize these bio-based nanomaterials, that may not require further reduction to more stable secondary amines.

Original language	English
Pages (from-to)	9408-9411
Journal	Chemical Communications
Volume	59
Issue number	61
DOIs	https://doi.org/10.1039/D3CC01329D
Publication status	Published - 4 Jul 2023
MoE publication type	A1 Journal article-refereed

Access to Document

10.1039/D3CC01329DLicence: CC BY

Cite this

@article{5ce806ec218f493a89f83e6c9bae2375,

title = "Stable glycosylamines at the reducing ends of cellulose nanocrystals",

abstract = "The reaction of reducing end groups in cellulose nanocrystals with dodecylamine was examined. Using a direct-dissolution solution-state NMR protocol, the regioselective formation of glucosylamines was shown. This provides an elegant approach to sustainably functionalize these bio-based nanomaterials, that may not require further reduction to more stable secondary amines.",

author = "Jingwen Xia and Tetyana Koso and Katja Heise and Lukas Fliri and Emilie Ressouche and Johanna Majoinen and Kostiainen, \{Mauri A.\} and Sami Hietala and Michael Hummel and Vladimir Aseyev and Ilkka Kilpel{\"a}inen and King, \{Alistair W.T.\}",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2023",

month = jul,

day = "4",

doi = "10.1039/D3CC01329D",

language = "English",

volume = "59",

pages = "9408--9411",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry RSC",

number = "61",

}

TY - JOUR

T1 - Stable glycosylamines at the reducing ends of cellulose nanocrystals

AU - Xia, Jingwen

AU - Koso, Tetyana

AU - Heise, Katja

AU - Fliri, Lukas

AU - Ressouche, Emilie

AU - Majoinen, Johanna

AU - Kostiainen, Mauri A.

AU - Hietala, Sami

AU - Hummel, Michael

AU - Aseyev, Vladimir

AU - Kilpeläinen, Ilkka

AU - King, Alistair W.T.

PY - 2023/7/4

Y1 - 2023/7/4

N2 - The reaction of reducing end groups in cellulose nanocrystals with dodecylamine was examined. Using a direct-dissolution solution-state NMR protocol, the regioselective formation of glucosylamines was shown. This provides an elegant approach to sustainably functionalize these bio-based nanomaterials, that may not require further reduction to more stable secondary amines.

AB - The reaction of reducing end groups in cellulose nanocrystals with dodecylamine was examined. Using a direct-dissolution solution-state NMR protocol, the regioselective formation of glucosylamines was shown. This provides an elegant approach to sustainably functionalize these bio-based nanomaterials, that may not require further reduction to more stable secondary amines.

UR - https://www.scopus.com/pages/publications/85166161922

U2 - 10.1039/D3CC01329D

DO - 10.1039/D3CC01329D

M3 - Article

SN - 1359-7345

VL - 59

SP - 9408

EP - 9411

JO - Chemical Communications

JF - Chemical Communications

IS - 61

ER -

Stable glycosylamines at the reducing ends of cellulose nanocrystals

Abstract

Access to Document

Other files and links

Fingerprint

Cite this