Storage stability of bituminized reactor wastes

Petri Peltonen, Aarre Niemi

Research output: Book/ReportReportProfessional

Abstract

The aim of the research was to study the protection given by bitumen for nuclear waste in conditions of ground water storage during a time equivalent to the halflife of low and medium level radionuclides. The ageing of bitumen in road conditions and different kinds of water contacts was looked upon in the light of information obtained from background literature. The specimens of standard shape were kept in laboratory for six months in ground water conditions simulating the storage of bituminized resin wastes in steel drums deep in bedrock. The quality changes of bitumen and resin and bitumen mixtures were analysed by means of standard tests both before and after storage. In part dealing with background literature, it was estimated that the waste container would, in theory, remain undamaged for 200 years at most under the influence of internal pressure, swelling and corrosion. After this, gases will gain access through the first corroded spot to the ground water, and water-soluble salts will find their way through the embrittled bitumen film. The results obtained from lime water storage of bitumen (in literature) indicate that bitumen films and the surface layer of the structure cannot withstand unembrittled. The proportional distribution of bitumen components underwent a change already in a short-term storage: the number of asphaltenes rose and the resin and asphaltene ratio decreased. This, the rise in stiffness and growing compressibility indicate a slight embrittlement of bitumen. The structure of the are resin and bitumen mixture did not prevent the absorption of ground water through hair cracks and flaws - on the contrary, the specimens swelled by approximately 50 vol.%. The mixtures which contained ARA or powdered resin and bitumen swelled noticeably less, 3.0 and 0.6 vol.%, respectively. Bitumen repels water but diffusion of water may take place through a damaged bitumen film. Water penetrating under the films on the resin surface weakens adhesion. The considerable swelling of resins and internal gas formation weaken adhesion and also promote leaching. These phenomena noticeably weaken the effect of the otherwise excellent waterproofing properties of bitumen. To eliminate the risk of leaching the research report recommends that the steel drums be made thicker and that the amount of bitumen be increased depending on the degree of fineness of the resin type in question. It means that the fine resin type needs more bitumen than the granular resin type. The resin waste should, moreover, be surrounded by a sufficiently thick waterproofing layer of pure bitumen. For a follow-up research, it is suggested that a bituminization capsule which would contain bitumen and resin waste mixture and which would be immersed in bitumen be developed.
Original languageEnglish
Place of PublicationEspoo
PublisherVTT Technical Research Centre of Finland
Number of pages90
ISBN (Print)951-38-1898-5
Publication statusPublished - 1983
MoE publication typeD4 Published development or research report or study

Publication series

NameTutkimuksia / Valtion teknillinen tutkimuskeskus
PublisherVTT
Volume226
ISSN (Print)0358-5077

Fingerprint

Resins
Groundwater
Waterproofing
Water
Leaching
Swelling
Adhesion
Asphaltenes
Steel
Saline water
Embrittlement
Radioactive wastes
Gases
Compressibility
Radioisotopes
Lime
Containers
Aging of materials
Stiffness
Corrosion

Keywords

  • bitumens
  • durability
  • radioactive wastes
  • waste treatment

Cite this

Peltonen, P., & Niemi, A. (1983). Storage stability of bituminized reactor wastes. Espoo: VTT Technical Research Centre of Finland. Valtion teknillinen tutkimuskeskus. Tutkimuksia - Research Reports, No. 226
Peltonen, Petri ; Niemi, Aarre. / Storage stability of bituminized reactor wastes. Espoo : VTT Technical Research Centre of Finland, 1983. 90 p. (Valtion teknillinen tutkimuskeskus. Tutkimuksia - Research Reports; No. 226).
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Peltonen, P & Niemi, A 1983, Storage stability of bituminized reactor wastes. Valtion teknillinen tutkimuskeskus. Tutkimuksia - Research Reports, no. 226, VTT Technical Research Centre of Finland, Espoo.

Storage stability of bituminized reactor wastes. / Peltonen, Petri; Niemi, Aarre.

Espoo : VTT Technical Research Centre of Finland, 1983. 90 p. (Valtion teknillinen tutkimuskeskus. Tutkimuksia - Research Reports; No. 226).

Research output: Book/ReportReportProfessional

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AU - Niemi, Aarre

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N2 - The aim of the research was to study the protection given by bitumen for nuclear waste in conditions of ground water storage during a time equivalent to the halflife of low and medium level radionuclides. The ageing of bitumen in road conditions and different kinds of water contacts was looked upon in the light of information obtained from background literature. The specimens of standard shape were kept in laboratory for six months in ground water conditions simulating the storage of bituminized resin wastes in steel drums deep in bedrock. The quality changes of bitumen and resin and bitumen mixtures were analysed by means of standard tests both before and after storage. In part dealing with background literature, it was estimated that the waste container would, in theory, remain undamaged for 200 years at most under the influence of internal pressure, swelling and corrosion. After this, gases will gain access through the first corroded spot to the ground water, and water-soluble salts will find their way through the embrittled bitumen film. The results obtained from lime water storage of bitumen (in literature) indicate that bitumen films and the surface layer of the structure cannot withstand unembrittled. The proportional distribution of bitumen components underwent a change already in a short-term storage: the number of asphaltenes rose and the resin and asphaltene ratio decreased. This, the rise in stiffness and growing compressibility indicate a slight embrittlement of bitumen. The structure of the are resin and bitumen mixture did not prevent the absorption of ground water through hair cracks and flaws - on the contrary, the specimens swelled by approximately 50 vol.%. The mixtures which contained ARA or powdered resin and bitumen swelled noticeably less, 3.0 and 0.6 vol.%, respectively. Bitumen repels water but diffusion of water may take place through a damaged bitumen film. Water penetrating under the films on the resin surface weakens adhesion. The considerable swelling of resins and internal gas formation weaken adhesion and also promote leaching. These phenomena noticeably weaken the effect of the otherwise excellent waterproofing properties of bitumen. To eliminate the risk of leaching the research report recommends that the steel drums be made thicker and that the amount of bitumen be increased depending on the degree of fineness of the resin type in question. It means that the fine resin type needs more bitumen than the granular resin type. The resin waste should, moreover, be surrounded by a sufficiently thick waterproofing layer of pure bitumen. For a follow-up research, it is suggested that a bituminization capsule which would contain bitumen and resin waste mixture and which would be immersed in bitumen be developed.

AB - The aim of the research was to study the protection given by bitumen for nuclear waste in conditions of ground water storage during a time equivalent to the halflife of low and medium level radionuclides. The ageing of bitumen in road conditions and different kinds of water contacts was looked upon in the light of information obtained from background literature. The specimens of standard shape were kept in laboratory for six months in ground water conditions simulating the storage of bituminized resin wastes in steel drums deep in bedrock. The quality changes of bitumen and resin and bitumen mixtures were analysed by means of standard tests both before and after storage. In part dealing with background literature, it was estimated that the waste container would, in theory, remain undamaged for 200 years at most under the influence of internal pressure, swelling and corrosion. After this, gases will gain access through the first corroded spot to the ground water, and water-soluble salts will find their way through the embrittled bitumen film. The results obtained from lime water storage of bitumen (in literature) indicate that bitumen films and the surface layer of the structure cannot withstand unembrittled. The proportional distribution of bitumen components underwent a change already in a short-term storage: the number of asphaltenes rose and the resin and asphaltene ratio decreased. This, the rise in stiffness and growing compressibility indicate a slight embrittlement of bitumen. The structure of the are resin and bitumen mixture did not prevent the absorption of ground water through hair cracks and flaws - on the contrary, the specimens swelled by approximately 50 vol.%. The mixtures which contained ARA or powdered resin and bitumen swelled noticeably less, 3.0 and 0.6 vol.%, respectively. Bitumen repels water but diffusion of water may take place through a damaged bitumen film. Water penetrating under the films on the resin surface weakens adhesion. The considerable swelling of resins and internal gas formation weaken adhesion and also promote leaching. These phenomena noticeably weaken the effect of the otherwise excellent waterproofing properties of bitumen. To eliminate the risk of leaching the research report recommends that the steel drums be made thicker and that the amount of bitumen be increased depending on the degree of fineness of the resin type in question. It means that the fine resin type needs more bitumen than the granular resin type. The resin waste should, moreover, be surrounded by a sufficiently thick waterproofing layer of pure bitumen. For a follow-up research, it is suggested that a bituminization capsule which would contain bitumen and resin waste mixture and which would be immersed in bitumen be developed.

KW - bitumens

KW - durability

KW - radioactive wastes

KW - waste treatment

M3 - Report

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BT - Storage stability of bituminized reactor wastes

PB - VTT Technical Research Centre of Finland

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ER -

Peltonen P, Niemi A. Storage stability of bituminized reactor wastes. Espoo: VTT Technical Research Centre of Finland, 1983. 90 p. (Valtion teknillinen tutkimuskeskus. Tutkimuksia - Research Reports; No. 226).