Abstract
The high cost of green hydrogen prevents the introduction of low-carbon hydrogen into the economy. This work aims to improve the profitability of water electrolysis by providing a holistic analysis of PEM electrolysis in steady and dynamic operation modes. In addition, additional streams of revenue are discussed, including the selling of waste heat from electrolysis and participating in electricity reserve markets. First, a data-driven model was developed to simulate the efficiency of PEM electrolysis as a function of loading percentage. Afterwards, the levelized cost of hydrogen (LCOH) was calculated in steady and dynamic operation modes. The sensitivity to capital cost assumptions, electrolyzer degradation rates, the efficiency profile of AC/DC rectifier, and the electricity profile was studied. It was found that dynamic operation affects the LCOH when compared with steady operation under identical electricity price profiles, ranging from decreasing the LCOH by 42 % to increasing the LCOH by 7.6 %. Moreover, each 1 µV/h increase in the electrolyzer degradation rate increases the LCOH by about 1.3–2.2 %. Conversely, utilizing electrolysis waste heat reduces the LCOH by 0.2–0.35 EUR/kg. Finally, the revenue from participating in electricity reserve markets could range from exceeding the total cost of green hydrogen production to not offsetting the increase in capital costs that result from a lower capacity factor. Overall, a holistic optimization of dynamic electrolysis operation is crucial to ensure that the reduction of LCOH from extra streams of revenue and lower electricity prices exceeds the increase in LCOH from a higher degradation rate and lower capacity factor.
| Original language | English |
|---|---|
| Article number | 116065 |
| Journal | Renewable and Sustainable Energy Reviews |
| Volume | 223 |
| DOIs | |
| Publication status | Published - Nov 2025 |
| MoE publication type | A1 Journal article-refereed |
Funding
The authors would like to acknowledge funding from the Fortum and Neste foundation with application number 20230118 .
Keywords
- Aspen plus®
- Degradation rate
- Demand response
- Dynamic operation
- Machine learning
- PEM electrolysis
- Waste heat
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