Structural study of lanthanum oxysulfate (LaO)2SO4

S. Zhukov (Corresponding Author), A. Yatsenko, V. Chernyshev, Vitali Trunov, E. Tserkovnaya, Olli Antson, Jorma Hölsä, P. Baules, H. Schenk

    Research output: Contribution to journalArticleScientificpeer-review

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    Abstract

    The structure of lanthanum oxysulfate (LaO)2SO4 was studied with neutron, electron, and X-ray diffraction using the Rietveld refinement method. The unit cell is determined to be monoclinic (a = 14.349(1), b = 4.2852(5), c = 8.386(1) Å, β = 107.00(1), Sp.gr. C2/c). The structure is similar to that of grandreefite and consists of the alternative sulfate and (LaO) layers. Every sulfate oxygen is coordinated with two lanthanum atoms. The experimental data were confirmed by the energy minimization calculations.
    Original languageEnglish
    Pages (from-to)43 - 50
    Number of pages8
    JournalMaterials Research Bulletin
    Volume32
    Issue number1
    DOIs
    Publication statusPublished - 1997
    MoE publication typeA1 Journal article-refereed

    Fingerprint

    Lanthanum
    lanthanum
    Rietveld refinement
    sulfates
    Sulfates
    Neutrons
    Oxygen
    X ray diffraction
    Atoms
    Electrons
    neutrons
    optimization
    oxygen
    cells
    diffraction
    atoms
    electrons
    x rays
    energy
    lanthanum sulfate

    Cite this

    Zhukov, S., Yatsenko, A., Chernyshev, V., Trunov, V., Tserkovnaya, E., Antson, O., ... Schenk, H. (1997). Structural study of lanthanum oxysulfate (LaO)2SO4. Materials Research Bulletin, 32(1), 43 - 50. https://doi.org/10.1016/S0025-5408(96)00159-6
    Zhukov, S. ; Yatsenko, A. ; Chernyshev, V. ; Trunov, Vitali ; Tserkovnaya, E. ; Antson, Olli ; Hölsä, Jorma ; Baules, P. ; Schenk, H. / Structural study of lanthanum oxysulfate (LaO)2SO4. In: Materials Research Bulletin. 1997 ; Vol. 32, No. 1. pp. 43 - 50.
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    title = "Structural study of lanthanum oxysulfate (LaO)2SO4",
    abstract = "The structure of lanthanum oxysulfate (LaO)2SO4 was studied with neutron, electron, and X-ray diffraction using the Rietveld refinement method. The unit cell is determined to be monoclinic (a = 14.349(1), b = 4.2852(5), c = 8.386(1) {\AA}, β = 107.00(1), Sp.gr. C2/c). The structure is similar to that of grandreefite and consists of the alternative sulfate and (LaO) layers. Every sulfate oxygen is coordinated with two lanthanum atoms. The experimental data were confirmed by the energy minimization calculations.",
    author = "S. Zhukov and A. Yatsenko and V. Chernyshev and Vitali Trunov and E. Tserkovnaya and Olli Antson and Jorma H{\"o}ls{\"a} and P. Baules and H. Schenk",
    year = "1997",
    doi = "10.1016/S0025-5408(96)00159-6",
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    Zhukov, S, Yatsenko, A, Chernyshev, V, Trunov, V, Tserkovnaya, E, Antson, O, Hölsä, J, Baules, P & Schenk, H 1997, 'Structural study of lanthanum oxysulfate (LaO)2SO4', Materials Research Bulletin, vol. 32, no. 1, pp. 43 - 50. https://doi.org/10.1016/S0025-5408(96)00159-6

    Structural study of lanthanum oxysulfate (LaO)2SO4. / Zhukov, S. (Corresponding Author); Yatsenko, A.; Chernyshev, V.; Trunov, Vitali; Tserkovnaya, E.; Antson, Olli; Hölsä, Jorma; Baules, P.; Schenk, H.

    In: Materials Research Bulletin, Vol. 32, No. 1, 1997, p. 43 - 50.

    Research output: Contribution to journalArticleScientificpeer-review

    TY - JOUR

    T1 - Structural study of lanthanum oxysulfate (LaO)2SO4

    AU - Zhukov, S.

    AU - Yatsenko, A.

    AU - Chernyshev, V.

    AU - Trunov, Vitali

    AU - Tserkovnaya, E.

    AU - Antson, Olli

    AU - Hölsä, Jorma

    AU - Baules, P.

    AU - Schenk, H.

    PY - 1997

    Y1 - 1997

    N2 - The structure of lanthanum oxysulfate (LaO)2SO4 was studied with neutron, electron, and X-ray diffraction using the Rietveld refinement method. The unit cell is determined to be monoclinic (a = 14.349(1), b = 4.2852(5), c = 8.386(1) Å, β = 107.00(1), Sp.gr. C2/c). The structure is similar to that of grandreefite and consists of the alternative sulfate and (LaO) layers. Every sulfate oxygen is coordinated with two lanthanum atoms. The experimental data were confirmed by the energy minimization calculations.

    AB - The structure of lanthanum oxysulfate (LaO)2SO4 was studied with neutron, electron, and X-ray diffraction using the Rietveld refinement method. The unit cell is determined to be monoclinic (a = 14.349(1), b = 4.2852(5), c = 8.386(1) Å, β = 107.00(1), Sp.gr. C2/c). The structure is similar to that of grandreefite and consists of the alternative sulfate and (LaO) layers. Every sulfate oxygen is coordinated with two lanthanum atoms. The experimental data were confirmed by the energy minimization calculations.

    U2 - 10.1016/S0025-5408(96)00159-6

    DO - 10.1016/S0025-5408(96)00159-6

    M3 - Article

    VL - 32

    SP - 43

    EP - 50

    JO - Materials Research Bulletin

    JF - Materials Research Bulletin

    SN - 0025-5408

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    ER -

    Zhukov S, Yatsenko A, Chernyshev V, Trunov V, Tserkovnaya E, Antson O et al. Structural study of lanthanum oxysulfate (LaO)2SO4. Materials Research Bulletin. 1997;32(1):43 - 50. https://doi.org/10.1016/S0025-5408(96)00159-6