Study of Microstructure, Hydrogen Solubility, and Corrosion of Ta-Modified Zr–1Nb Alloys for Nuclear Applications

P. A. Ferreirós; E. C.Savoy Polack; L. A. Lanzani; P. R. Alonso; D. P. Quirós; J. I. Mieza; E. Zelaya; A. J. Knowles; G. H. Rubiolo

doi:10.1007/978-3-030-92381-5_129

Study of Microstructure, Hydrogen Solubility, and Corrosion of Ta-Modified Zr–1Nb Alloys for Nuclear Applications

P. A. Ferreirós^*, E. C.Savoy Polack, L. A. Lanzani, P. R. Alonso, D. P. Quirós, J. I. Mieza, E. Zelaya, A. J. Knowles, G. H. Rubiolo

^*Corresponding author for this work

Not published at VTT

Research output: Chapter in Book/Report/Conference proceeding › Conference article in proceedings › Scientific › peer-review

1 Citation (Scopus)

Abstract

Modified Zr–1Nb alloys with Ta additions is a potential strategy to improve structural alloys for nuclear reactors. The effects of Ta on microstructural stability and resistance to corrosion of Zr–1Nb alloys were systematically investigated and elucidated. The (α+ β) microstructure in Zr–1.05Nb, Zr–0.85Nb–0.20Ta, and Zr–0.85Nb–0.40Ta (wt.%) alloys were obtained with the following two thermomechanical processes after a water quenching from βZr: (a) annealed at 570 °C for 3840 h and (b) a combination of intermediate annealing temperatures and cold rolled steps. Quantitative EDS-TEM analysis together with DSC measurements were used to characterise the changes in phase compositions and the fraction of beta-phase precipitates. Hydrogen solubility was measured in alloys with the first annealed condition. The Ta additions increase the monotectic transformation temperature, improves the steam corrosion at 400 °C and 10 MPa up to 14 days, and decreases slightly the hydrogen solubility. The higher thermal microstructural stability compared to Ta-free Zr–1Nb alloys provides potential advantages for increases in operating temperature or acceleration of precipitation kinetics during thermomechanical processing.

Original language	English
Title of host publication	TMS 2022 151st Annual Meeting and Exhibition Supplemental Proceedings
Publisher	Springer
Pages	1352-1362
ISBN (Electronic)	978-3-030-92381-5
ISBN (Print)	978-3-030-92380-8, 978-3-030-92383-9
DOIs	https://doi.org/10.1007/978-3-030-92381-5_129
Publication status	Published - 2022
MoE publication type	A4 Article in a conference publication
Event	151st Annual Meeting and Exhibition of The Minerals, Metals and Materials Society, TMS 2022 - Anaheim, United States Duration: 27 Feb 2022 → 3 Mar 2022

Publication series

Series	Minerals, Metals and Materials Series
ISSN	2367-1181

Conference

Conference	151st Annual Meeting and Exhibition of The Minerals, Metals and Materials Society, TMS 2022
Country/Territory	United States
City	Anaheim
Period	27/02/22 → 3/03/22

Funding

This study was supported by FonCyT, through PICT-2015-2267 and PICT-2018-01671 projects and by UNSAM, through PAI 2020-80020190200024SM project. P.A. Ferreirós & A.J. Knowles acknowledge funding from the UK Engineering and Physical Sciences Research Council (EPSRC) Grant EP/T01220X/1. The authors would also like to thank Jóhan Pauli Magnussen for his help with the phase equilibrium modelling.

Keywords

Corrosion
Hydrogen solubility
Phase transformation
Ta addition
Zr–Nb alloys

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1007/978-3-030-92381-5_129

Cite this

Ferreirós, P. A., Polack, E. C. S., Lanzani, L. A., Alonso, P. R., Quirós, D. P., Mieza, J. I., Zelaya, E., Knowles, A. J., & Rubiolo, G. H. (2022). Study of Microstructure, Hydrogen Solubility, and Corrosion of Ta-Modified Zr–1Nb Alloys for Nuclear Applications. In TMS 2022 151st Annual Meeting and Exhibition Supplemental Proceedings (pp. 1352-1362). Springer. https://doi.org/10.1007/978-3-030-92381-5_129

@inproceedings{e69746d5e4d14a00a3d989d434513ba1,

title = "Study of Microstructure, Hydrogen Solubility, and Corrosion of Ta-Modified Zr–1Nb Alloys for Nuclear Applications",

abstract = "Modified Zr–1Nb alloys with Ta additions is a potential strategy to improve structural alloys for nuclear reactors. The effects of Ta on microstructural stability and resistance to corrosion of Zr–1Nb alloys were systematically investigated and elucidated. The (α+ β) microstructure in Zr–1.05Nb, Zr–0.85Nb–0.20Ta, and Zr–0.85Nb–0.40Ta (wt.\%) alloys were obtained with the following two thermomechanical processes after a water quenching from βZr: (a) annealed at 570 °C for 3840 h and (b) a combination of intermediate annealing temperatures and cold rolled steps. Quantitative EDS-TEM analysis together with DSC measurements were used to characterise the changes in phase compositions and the fraction of beta-phase precipitates. Hydrogen solubility was measured in alloys with the first annealed condition. The Ta additions increase the monotectic transformation temperature, improves the steam corrosion at 400 °C and 10 MPa up to 14 days, and decreases slightly the hydrogen solubility. The higher thermal microstructural stability compared to Ta-free Zr–1Nb alloys provides potential advantages for increases in operating temperature or acceleration of precipitation kinetics during thermomechanical processing.",

keywords = "Corrosion, Hydrogen solubility, Phase transformation, Ta addition, Zr–Nb alloys",

author = "Ferreir{\'o}s, \{P. A.\} and Polack, \{E. C.Savoy\} and Lanzani, \{L. A.\} and Alonso, \{P. R.\} and Quir{\'o}s, \{D. P.\} and Mieza, \{J. I.\} and E. Zelaya and Knowles, \{A. J.\} and Rubiolo, \{G. H.\}",

note = "Funding Information: This study was supported by FonCyT, through PICT-2015-2267 and PICT-2018-01671 projects and by UNSAM, through PAI 2020-80020190200024SM project. P.A. Ferreir{\'o}s \& A.J. Knowles acknowledge funding from the UK Engineering and Physical Sciences Research Council (EPSRC) Grant EP/T01220X/1. The authors would also like to thank J{\'o}han Pauli Magnussen for his help with the phase equilibrium modelling. Publisher Copyright: {\textcopyright} 2022, The Minerals, Metals \& Materials Society.; 151st Annual Meeting and Exhibition of The Minerals, Metals and Materials Society, TMS 2022 ; Conference date: 27-02-2022 Through 03-03-2022",

year = "2022",

doi = "10.1007/978-3-030-92381-5\_129",

language = "English",

isbn = "978-3-030-92380-8",

series = "Minerals, Metals and Materials Series",

publisher = "Springer",

pages = "1352--1362",

booktitle = "TMS 2022 151st Annual Meeting and Exhibition Supplemental Proceedings",

address = "Germany",

}

Ferreirós, PA, Polack, ECS, Lanzani, LA, Alonso, PR, Quirós, DP, Mieza, JI, Zelaya, E, Knowles, AJ & Rubiolo, GH 2022, Study of Microstructure, Hydrogen Solubility, and Corrosion of Ta-Modified Zr–1Nb Alloys for Nuclear Applications. in TMS 2022 151st Annual Meeting and Exhibition Supplemental Proceedings. Springer, Minerals, Metals and Materials Series, pp. 1352-1362, 151st Annual Meeting and Exhibition of The Minerals, Metals and Materials Society, TMS 2022, Anaheim, United States, 27/02/22. https://doi.org/10.1007/978-3-030-92381-5_129

Study of Microstructure, Hydrogen Solubility, and Corrosion of Ta-Modified Zr–1Nb Alloys for Nuclear Applications. / Ferreirós, P. A.; Polack, E. C.Savoy; Lanzani, L. A. et al.
TMS 2022 151st Annual Meeting and Exhibition Supplemental Proceedings. Springer, 2022. p. 1352-1362 (Minerals, Metals and Materials Series).

Research output: Chapter in Book/Report/Conference proceeding › Conference article in proceedings › Scientific › peer-review

TY - GEN

T1 - Study of Microstructure, Hydrogen Solubility, and Corrosion of Ta-Modified Zr–1Nb Alloys for Nuclear Applications

AU - Ferreirós, P. A.

AU - Polack, E. C.Savoy

AU - Lanzani, L. A.

AU - Alonso, P. R.

AU - Quirós, D. P.

AU - Mieza, J. I.

AU - Zelaya, E.

AU - Knowles, A. J.

AU - Rubiolo, G. H.

N1 - Funding Information: This study was supported by FonCyT, through PICT-2015-2267 and PICT-2018-01671 projects and by UNSAM, through PAI 2020-80020190200024SM project. P.A. Ferreirós & A.J. Knowles acknowledge funding from the UK Engineering and Physical Sciences Research Council (EPSRC) Grant EP/T01220X/1. The authors would also like to thank Jóhan Pauli Magnussen for his help with the phase equilibrium modelling. Publisher Copyright: © 2022, The Minerals, Metals & Materials Society.

PY - 2022

Y1 - 2022

N2 - Modified Zr–1Nb alloys with Ta additions is a potential strategy to improve structural alloys for nuclear reactors. The effects of Ta on microstructural stability and resistance to corrosion of Zr–1Nb alloys were systematically investigated and elucidated. The (α+ β) microstructure in Zr–1.05Nb, Zr–0.85Nb–0.20Ta, and Zr–0.85Nb–0.40Ta (wt.%) alloys were obtained with the following two thermomechanical processes after a water quenching from βZr: (a) annealed at 570 °C for 3840 h and (b) a combination of intermediate annealing temperatures and cold rolled steps. Quantitative EDS-TEM analysis together with DSC measurements were used to characterise the changes in phase compositions and the fraction of beta-phase precipitates. Hydrogen solubility was measured in alloys with the first annealed condition. The Ta additions increase the monotectic transformation temperature, improves the steam corrosion at 400 °C and 10 MPa up to 14 days, and decreases slightly the hydrogen solubility. The higher thermal microstructural stability compared to Ta-free Zr–1Nb alloys provides potential advantages for increases in operating temperature or acceleration of precipitation kinetics during thermomechanical processing.

AB - Modified Zr–1Nb alloys with Ta additions is a potential strategy to improve structural alloys for nuclear reactors. The effects of Ta on microstructural stability and resistance to corrosion of Zr–1Nb alloys were systematically investigated and elucidated. The (α+ β) microstructure in Zr–1.05Nb, Zr–0.85Nb–0.20Ta, and Zr–0.85Nb–0.40Ta (wt.%) alloys were obtained with the following two thermomechanical processes after a water quenching from βZr: (a) annealed at 570 °C for 3840 h and (b) a combination of intermediate annealing temperatures and cold rolled steps. Quantitative EDS-TEM analysis together with DSC measurements were used to characterise the changes in phase compositions and the fraction of beta-phase precipitates. Hydrogen solubility was measured in alloys with the first annealed condition. The Ta additions increase the monotectic transformation temperature, improves the steam corrosion at 400 °C and 10 MPa up to 14 days, and decreases slightly the hydrogen solubility. The higher thermal microstructural stability compared to Ta-free Zr–1Nb alloys provides potential advantages for increases in operating temperature or acceleration of precipitation kinetics during thermomechanical processing.

KW - Corrosion

KW - Hydrogen solubility

KW - Phase transformation

KW - Ta addition

KW - Zr–Nb alloys

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U2 - 10.1007/978-3-030-92381-5_129

DO - 10.1007/978-3-030-92381-5_129

M3 - Conference article in proceedings

AN - SCOPUS:85125263987

SN - 978-3-030-92380-8

SN - 978-3-030-92383-9

T3 - Minerals, Metals and Materials Series

SP - 1352

EP - 1362

BT - TMS 2022 151st Annual Meeting and Exhibition Supplemental Proceedings

PB - Springer

T2 - 151st Annual Meeting and Exhibition of The Minerals, Metals and Materials Society, TMS 2022

Y2 - 27 February 2022 through 3 March 2022

ER -

Ferreirós PA, Polack ECS, Lanzani LA, Alonso PR, Quirós DP, Mieza JI et al. Study of Microstructure, Hydrogen Solubility, and Corrosion of Ta-Modified Zr–1Nb Alloys for Nuclear Applications. In TMS 2022 151st Annual Meeting and Exhibition Supplemental Proceedings. Springer. 2022. p. 1352-1362. (Minerals, Metals and Materials Series). doi: 10.1007/978-3-030-92381-5_129

Study of Microstructure, Hydrogen Solubility, and Corrosion of Ta-Modified Zr–1Nb Alloys for Nuclear Applications

Abstract

Publication series

Conference

Funding

Keywords

UN SDGs

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