Sulphur poisoning of nickel-based hot gas cleaning catalysts in synthetic gasification gas: I. Effect of different process parameters

Jouko Hepola (Corresponding Author), Pekka Simell

Research output: Contribution to journalArticleScientificpeer-review

75 Citations (Scopus)

Abstract

The effect of different process parameters on sulphur poisoning of nickel catalysts in tar (toluene), ammonia and methane decomposition was studied. Tests were carried out in a fixed-bed tube reactor at 800–1000°C at 5 and under 20 bar total pressure using a synthetic gasification gas mixture. In the same conditions, sulphur affected less the toluene and methane decomposing activity than the ammonia decomposing activity. Ammonia conversion was affected by the catalyst type but not by the nickel content of catalyst. When temperature was increased the effect of sulphur poisoning was decreased. At 20 bar pressure the poisoning effect of sulphur was stronger than at 5 bar pressure. To prevent sulphur poisoning of nickel catalysts in the tar and ammonia decomposition process at high pressure (20–30 bar), the catalyst process should operate at > 900°C. In addition, by decreasing the space velocity of the process the sulphur poisoning effect could be compensated in the test conditions.

Original languageEnglish
Pages (from-to)287 - 303
Number of pages17
JournalApplied Catalysis B: Environmental
Volume14
Issue number3-4
DOIs
Publication statusPublished - 1997
MoE publication typeA1 Journal article-refereed

Keywords

  • gasification

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