Surface composition of stainless steel at active corrosion

Tero Hakkarainen; Ingemar Olefjord

doi:10.1088/0031-8949/1983/T4/043

Surface composition of stainless steel at active corrosion

Tero Hakkarainen, Ingemar Olefjord

VTT Technical Research Centre of Finland

Chalmers University of Technology

Research output: Contribution to journal › Article › Scientific › peer-review

Abstract

X-ray photo-electron spectroscopy was used to study the surface composition of stainless steel (AISI 304) after active corrosion in 2.5 M H₂SO₄ or 2.5 M H₂SO₄ + 0.5 M NaCl solutions under electrochemically controlled conditions. Using two models with different assumptions about the element distributions, possible concentration profiles for Fe, Cr, Ni, Mo and Cu in their metallic and oxidized states were evaluated. It was concluded that Ni, Cu and Mo are enriched in their metallic states on the surface, possibly mainly on separate surface regions not containing Fe and Cr.

Original language	English
Pages (from-to)	189-193
Journal	Physica Scripta
Volume	T4
DOIs	https://doi.org/10.1088/0031-8949/1983/T4/043
Publication status	Published - 1983
MoE publication type	A1 Journal article-refereed

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title = "Surface composition of stainless steel at active corrosion",

abstract = "X-ray photo-electron spectroscopy was used to study the surface composition of stainless steel (AISI 304) after active corrosion in 2.5 M H2SO4 or 2.5 M H2SO4 + 0.5 M NaCl solutions under electrochemically controlled conditions. Using two models with different assumptions about the element distributions, possible concentration profiles for Fe, Cr, Ni, Mo and Cu in their metallic and oxidized states were evaluated. It was concluded that Ni, Cu and Mo are enriched in their metallic states on the surface, possibly mainly on separate surface regions not containing Fe and Cr. ",

author = "Tero Hakkarainen and Ingemar Olefjord",

year = "1983",

doi = "10.1088/0031-8949/1983/T4/043",

language = "English",

volume = "T4",

pages = "189--193",

journal = "Physica Scripta",

issn = "0281-1847",

publisher = "Institute of Physics IOP",

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TY - JOUR

T1 - Surface composition of stainless steel at active corrosion

AU - Hakkarainen, Tero

AU - Olefjord, Ingemar

PY - 1983

Y1 - 1983

N2 - X-ray photo-electron spectroscopy was used to study the surface composition of stainless steel (AISI 304) after active corrosion in 2.5 M H2SO4 or 2.5 M H2SO4 + 0.5 M NaCl solutions under electrochemically controlled conditions. Using two models with different assumptions about the element distributions, possible concentration profiles for Fe, Cr, Ni, Mo and Cu in their metallic and oxidized states were evaluated. It was concluded that Ni, Cu and Mo are enriched in their metallic states on the surface, possibly mainly on separate surface regions not containing Fe and Cr.

AB - X-ray photo-electron spectroscopy was used to study the surface composition of stainless steel (AISI 304) after active corrosion in 2.5 M H2SO4 or 2.5 M H2SO4 + 0.5 M NaCl solutions under electrochemically controlled conditions. Using two models with different assumptions about the element distributions, possible concentration profiles for Fe, Cr, Ni, Mo and Cu in their metallic and oxidized states were evaluated. It was concluded that Ni, Cu and Mo are enriched in their metallic states on the surface, possibly mainly on separate surface regions not containing Fe and Cr.

U2 - 10.1088/0031-8949/1983/T4/043

DO - 10.1088/0031-8949/1983/T4/043

M3 - Article

SN - 0281-1847

VL - T4

SP - 189

EP - 193

JO - Physica Scripta

JF - Physica Scripta

ER -

Surface composition of stainless steel at active corrosion

Abstract

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