Surface initiated polymerization of a cationic monomer on inner surfaces of silica capillaries: Analyte separation by capillary electrophoresis versus polyelectrolyte behavior.

Joanna Witos; Mikko Karesoja; Erno Karjalainen; Heikki Tenhu; Marja-Liisa Riekkola

doi:10.1002/jssc.201200945

Surface initiated polymerization of a cationic monomer on inner surfaces of silica capillaries: Analyte separation by capillary electrophoresis versus polyelectrolyte behavior.

Joanna Witos, Mikko Karesoja, Erno Karjalainen, Heikki Tenhu, Marja-Liisa Riekkola^*

^*Corresponding author for this work

Not published at VTT

University of Helsinki

Research output: Contribution to journal › Article › Scientific › peer-review

14 Citations (Scopus)

Abstract

[2-(Methacryloyl)oxyethyl]trimethylammonium chloride was successfully polymd. by surface-initiated atom transfer radical polymn. method on the inner surface of fused-silica capillaries resulting in a covalently bound poly([2-(methacryloyl)oxyethyl]trimethylammonium chloride) coating. The coated capillaries provided in capillary electrophoresis an excellent run-to-run repeatability, capillary-to-capillary and day-to-day reproducibility. The capillaries worked reliably over 1 mo with EOF repeatability

Original language	English
Pages (from-to)	1070-1077
Journal	Journal of Separation Science
Volume	36
Issue number	6
DOIs	https://doi.org/10.1002/jssc.201200945
Publication status	Published - 2013
MoE publication type	A1 Journal article-refereed

Keywords

Polymerization (atom transfer
radical
surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis)
IR spectra (of poly([2-(methacryloyl)oxyethyl]trimethylammonium chloride) coating on inner surfaces of silica capillaries)
Capillary electrophoresis
Polyelectrolytes (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis)
Î²-Adrenoceptor antagonists (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for capillary electrophoresis for sepn. of)
High-density lipoproteins
Low-density lipoproteins
Proteins Role: ANT (Analyte)
ANST (Analytical study) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for capillary electrophoresis for sepn. of)
methacryloyloxyethyltrimethylammonium
chloride
surface
initiated
polymn
fused
silica
capillary
electrophoresis

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10.1002/jssc.201200945

Cite this

@article{fe73173fe980451fb175dfce650d016a,

title = "Surface initiated polymerization of a cationic monomer on inner surfaces of silica capillaries: Analyte separation by capillary electrophoresis versus polyelectrolyte behavior.",

abstract = "[2-(Methacryloyl)oxyethyl]trimethylammonium chloride was successfully polymd. by surface-initiated atom transfer radical polymn. method on the inner surface of fused-silica capillaries resulting in a covalently bound poly([2-(methacryloyl)oxyethyl]trimethylammonium chloride) coating. The coated capillaries provided in capillary electrophoresis an excellent run-to-run repeatability, capillary-to-capillary and day-to-day reproducibility. The capillaries worked reliably over 1 mo with EOF repeatability ",

keywords = "Polymerization (atom transfer, radical, surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis), IR spectra (of poly([2-(methacryloyl)oxyethyl]trimethylammonium chloride) coating on inner surfaces of silica capillaries), Capillary electrophoresis, Polyelectrolytes (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis), {\^I}²-Adrenoceptor antagonists (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for capillary electrophoresis for sepn. of), High-density lipoproteins, Low-density lipoproteins, Proteins Role: ANT (Analyte), ANST (Analytical study) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for capillary electrophoresis for sepn. of), methacryloyloxyethyltrimethylammonium, chloride, surface, initiated, polymn, fused, silica, capillary, electrophoresis",

author = "Joanna Witos and Mikko Karesoja and Erno Karjalainen and Heikki Tenhu and Marja-Liisa Riekkola",

note = "Copyright (C) 2014 American Chemical Society (ACS). All Rights Reserved.; Section Code: 80-4; CA Section Cross-references: 9; CODEN: JSSCCJ; CAS Registry Numbers: 71-50-1 (Acetate); 14265-44-2 (Phosphate) Role: ARU (Analytical role, unclassified), NUU (Other use, unclassified), ANST (Analytical study), USES (Uses) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis); 60676-86-0 (Fused-silica) Role: ARU (Analytical role, unclassified), RCT (Reactant), TEM (Technical or engineered material use), ANST (Analytical study), USES (Uses), RACT (Reactant or reagent) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis); 26161-33-1P ([2-(Methacryloyl)oxyethyl]trimethylammonium chloride homopolymer) Role: ARU (Analytical role, unclassified), SPN (Synthetic preparation), TEM (Technical or engineered material use), ANST (Analytical study), PREP (Preparation), USES (Uses) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis); 78-67-1 (AIBN) Role: CAT (Catalyst use), USES (Uses) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis); 5039-78-1 ([2-(Methacryloyl)oxyethyl]trimethylammonium chloride) Role: RCT (Reactant), RACT (Reactant or reagent) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis); 255727-67-4P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis); 366-18-7 (2,2'-Bipyridyl); 7787-70-4 (Copper(I) bromide); 1429926-46-4 Role: RGT (Reagent), RACT (Reactant or reagent) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis); 9001-63-2 (Lysozyme); 9007-43-6 (Cytochrome c); 9035-75-0 ({\^I}±-Chymotrypsinogen); 13523-86-9 (Pindolol); 13655-52-2 (Alprenolol); 29122-68-7 (Atenolol); 36894-69-6 (Labetalol); 51384-51-1 (Metoprolol) Role: ANT (Analyte), ANST (Analytical study) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for capillary electrophoresis for sepn. of)",

year = "2013",

doi = "10.1002/jssc.201200945",

language = "English",

volume = "36",

pages = "1070--1077",

journal = "Journal of Separation Science",

issn = "1615-9306",

publisher = "Wiley",

number = "6",

}

Surface initiated polymerization of a cationic monomer on inner surfaces of silica capillaries: Analyte separation by capillary electrophoresis versus polyelectrolyte behavior. / Witos, Joanna; Karesoja, Mikko; Karjalainen, Erno et al.
In: Journal of Separation Science, Vol. 36, No. 6, 2013, p. 1070-1077.

Research output: Contribution to journal › Article › Scientific › peer-review

TY - JOUR

T1 - Surface initiated polymerization of a cationic monomer on inner surfaces of silica capillaries: Analyte separation by capillary electrophoresis versus polyelectrolyte behavior.

AU - Witos, Joanna

AU - Karesoja, Mikko

AU - Karjalainen, Erno

AU - Tenhu, Heikki

AU - Riekkola, Marja-Liisa

N1 - Copyright (C) 2014 American Chemical Society (ACS). All Rights Reserved.; Section Code: 80-4; CA Section Cross-references: 9; CODEN: JSSCCJ; CAS Registry Numbers: 71-50-1 (Acetate); 14265-44-2 (Phosphate) Role: ARU (Analytical role, unclassified), NUU (Other use, unclassified), ANST (Analytical study), USES (Uses) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis); 60676-86-0 (Fused-silica) Role: ARU (Analytical role, unclassified), RCT (Reactant), TEM (Technical or engineered material use), ANST (Analytical study), USES (Uses), RACT (Reactant or reagent) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis); 26161-33-1P ([2-(Methacryloyl)oxyethyl]trimethylammonium chloride homopolymer) Role: ARU (Analytical role, unclassified), SPN (Synthetic preparation), TEM (Technical or engineered material use), ANST (Analytical study), PREP (Preparation), USES (Uses) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis); 78-67-1 (AIBN) Role: CAT (Catalyst use), USES (Uses) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis); 5039-78-1 ([2-(Methacryloyl)oxyethyl]trimethylammonium chloride) Role: RCT (Reactant), RACT (Reactant or reagent) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis); 255727-67-4P Role: RCT (Reactant), SPN (Synthetic preparation), PREP (Preparation), RACT (Reactant or reagent) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis); 366-18-7 (2,2'-Bipyridyl); 7787-70-4 (Copper(I) bromide); 1429926-46-4 Role: RGT (Reagent), RACT (Reactant or reagent) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis); 9001-63-2 (Lysozyme); 9007-43-6 (Cytochrome c); 9035-75-0 (Î±-Chymotrypsinogen); 13523-86-9 (Pindolol); 13655-52-2 (Alprenolol); 29122-68-7 (Atenolol); 36894-69-6 (Labetalol); 51384-51-1 (Metoprolol) Role: ANT (Analyte), ANST (Analytical study) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for capillary electrophoresis for sepn. of)

PY - 2013

Y1 - 2013

N2 - [2-(Methacryloyl)oxyethyl]trimethylammonium chloride was successfully polymd. by surface-initiated atom transfer radical polymn. method on the inner surface of fused-silica capillaries resulting in a covalently bound poly([2-(methacryloyl)oxyethyl]trimethylammonium chloride) coating. The coated capillaries provided in capillary electrophoresis an excellent run-to-run repeatability, capillary-to-capillary and day-to-day reproducibility. The capillaries worked reliably over 1 mo with EOF repeatability

AB - [2-(Methacryloyl)oxyethyl]trimethylammonium chloride was successfully polymd. by surface-initiated atom transfer radical polymn. method on the inner surface of fused-silica capillaries resulting in a covalently bound poly([2-(methacryloyl)oxyethyl]trimethylammonium chloride) coating. The coated capillaries provided in capillary electrophoresis an excellent run-to-run repeatability, capillary-to-capillary and day-to-day reproducibility. The capillaries worked reliably over 1 mo with EOF repeatability

KW - Polymerization (atom transfer

KW - radical

KW - surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis)

KW - IR spectra (of poly([2-(methacryloyl)oxyethyl]trimethylammonium chloride) coating on inner surfaces of silica capillaries)

KW - Capillary electrophoresis

KW - Polyelectrolytes (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for analyte sepn. by capillary electrophoresis)

KW - Î²-Adrenoceptor antagonists (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for capillary electrophoresis for sepn. of)

KW - High-density lipoproteins

KW - Low-density lipoproteins

KW - Proteins Role: ANT (Analyte)

KW - ANST (Analytical study) (surface initiated polymn. of cationic monomer on inner surfaces of silica capillaries for capillary electrophoresis for sepn. of)

KW - methacryloyloxyethyltrimethylammonium

KW - chloride

KW - surface

KW - initiated

KW - polymn

KW - fused

KW - silica

KW - capillary

KW - electrophoresis

U2 - 10.1002/jssc.201200945

DO - 10.1002/jssc.201200945

M3 - Article

SN - 1615-9306

VL - 36

SP - 1070

EP - 1077

JO - Journal of Separation Science

JF - Journal of Separation Science

IS - 6

ER -

Surface initiated polymerization of a cationic monomer on inner surfaces of silica capillaries: Analyte separation by capillary electrophoresis versus polyelectrolyte behavior.

Abstract

Keywords

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