Surface modification of nanocellulose membranes using thermoresponsive poly(N-isopropylacrylamide)

Minna Hakalahti, Tuomas Hänninen, Harri Setälä, Zohep Karim, Aji P. Mathew, Andreas Mautner, Alexander Bismarck, Tekla Tammelin

Research output: Contribution to conferenceConference AbstractScientific

Abstract

Cellulose nanofibers (CNF) can be regarded as biodegradable and biobased alternatives for synthetic membrane materials. Carboxylic acid groups containing TEMPO oxidized CNF is highly anionic and can be used e.g. for scavenging of contaminants, such as cationic metal ions from waste water. Water stable membranes were prepared from TEMPO oxidized CNF with an addition of 10 w-% of poly(vinyl alcohol) (PVA). The water permeability of the membrane is in the reverse osmosis membrane region. Furthermore, a surface modification route in order to attach a thermoresponsive poly(N-isopropylacrylamide) group directly on nanocellulosic (TEMPO-PVA materials and unmodified CNF based materials) membrane surfaces was developed. Effects of surface modification on the membranes structure and properties were evaluated.
Original languageEnglish
Publication statusPublished - 2014
Event4th Dissemination workshop of the Nano4water cluster: Nanoenabled systems and membranes for water treatment - Stockholm, Sweden
Duration: 23 Apr 201424 Apr 2014
Conference number: 4

Workshop

Workshop4th Dissemination workshop of the Nano4water cluster
CountrySweden
CityStockholm
Period23/04/1424/04/14

Fingerprint

Nanofibers
Surface treatment
oxidized cellulose
Membranes
Cellulose
Osmosis membranes
Membrane structures
Water
Scavenging
Reverse osmosis
Carboxylic Acids
Metal ions
Wastewater
Alcohols
Impurities
poly-N-isopropylacrylamide
TEMPO

Cite this

Hakalahti, M., Hänninen, T., Setälä, H., Karim, Z., Mathew, A. P., Mautner, A., ... Tammelin, T. (2014). Surface modification of nanocellulose membranes using thermoresponsive poly(N-isopropylacrylamide). Abstract from 4th Dissemination workshop of the Nano4water cluster, Stockholm, Sweden.
Hakalahti, Minna ; Hänninen, Tuomas ; Setälä, Harri ; Karim, Zohep ; Mathew, Aji P. ; Mautner, Andreas ; Bismarck, Alexander ; Tammelin, Tekla. / Surface modification of nanocellulose membranes using thermoresponsive poly(N-isopropylacrylamide). Abstract from 4th Dissemination workshop of the Nano4water cluster, Stockholm, Sweden.
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title = "Surface modification of nanocellulose membranes using thermoresponsive poly(N-isopropylacrylamide)",
abstract = "Cellulose nanofibers (CNF) can be regarded as biodegradable and biobased alternatives for synthetic membrane materials. Carboxylic acid groups containing TEMPO oxidized CNF is highly anionic and can be used e.g. for scavenging of contaminants, such as cationic metal ions from waste water. Water stable membranes were prepared from TEMPO oxidized CNF with an addition of 10 w-{\%} of poly(vinyl alcohol) (PVA). The water permeability of the membrane is in the reverse osmosis membrane region. Furthermore, a surface modification route in order to attach a thermoresponsive poly(N-isopropylacrylamide) group directly on nanocellulosic (TEMPO-PVA materials and unmodified CNF based materials) membrane surfaces was developed. Effects of surface modification on the membranes structure and properties were evaluated.",
author = "Minna Hakalahti and Tuomas H{\"a}nninen and Harri Set{\"a}l{\"a} and Zohep Karim and Mathew, {Aji P.} and Andreas Mautner and Alexander Bismarck and Tekla Tammelin",
note = "LIS: abstract reviewed SDA: SHP: Bioeconomy; 4th Dissemination workshop of the Nano4water cluster : Nanoenabled systems and membranes for water treatment ; Conference date: 23-04-2014 Through 24-04-2014",
year = "2014",
language = "English",

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Hakalahti, M, Hänninen, T, Setälä, H, Karim, Z, Mathew, AP, Mautner, A, Bismarck, A & Tammelin, T 2014, 'Surface modification of nanocellulose membranes using thermoresponsive poly(N-isopropylacrylamide)' 4th Dissemination workshop of the Nano4water cluster, Stockholm, Sweden, 23/04/14 - 24/04/14, .

Surface modification of nanocellulose membranes using thermoresponsive poly(N-isopropylacrylamide). / Hakalahti, Minna; Hänninen, Tuomas; Setälä, Harri; Karim, Zohep; Mathew, Aji P.; Mautner, Andreas; Bismarck, Alexander; Tammelin, Tekla.

2014. Abstract from 4th Dissemination workshop of the Nano4water cluster, Stockholm, Sweden.

Research output: Contribution to conferenceConference AbstractScientific

TY - CONF

T1 - Surface modification of nanocellulose membranes using thermoresponsive poly(N-isopropylacrylamide)

AU - Hakalahti, Minna

AU - Hänninen, Tuomas

AU - Setälä, Harri

AU - Karim, Zohep

AU - Mathew, Aji P.

AU - Mautner, Andreas

AU - Bismarck, Alexander

AU - Tammelin, Tekla

N1 - LIS: abstract reviewed SDA: SHP: Bioeconomy

PY - 2014

Y1 - 2014

N2 - Cellulose nanofibers (CNF) can be regarded as biodegradable and biobased alternatives for synthetic membrane materials. Carboxylic acid groups containing TEMPO oxidized CNF is highly anionic and can be used e.g. for scavenging of contaminants, such as cationic metal ions from waste water. Water stable membranes were prepared from TEMPO oxidized CNF with an addition of 10 w-% of poly(vinyl alcohol) (PVA). The water permeability of the membrane is in the reverse osmosis membrane region. Furthermore, a surface modification route in order to attach a thermoresponsive poly(N-isopropylacrylamide) group directly on nanocellulosic (TEMPO-PVA materials and unmodified CNF based materials) membrane surfaces was developed. Effects of surface modification on the membranes structure and properties were evaluated.

AB - Cellulose nanofibers (CNF) can be regarded as biodegradable and biobased alternatives for synthetic membrane materials. Carboxylic acid groups containing TEMPO oxidized CNF is highly anionic and can be used e.g. for scavenging of contaminants, such as cationic metal ions from waste water. Water stable membranes were prepared from TEMPO oxidized CNF with an addition of 10 w-% of poly(vinyl alcohol) (PVA). The water permeability of the membrane is in the reverse osmosis membrane region. Furthermore, a surface modification route in order to attach a thermoresponsive poly(N-isopropylacrylamide) group directly on nanocellulosic (TEMPO-PVA materials and unmodified CNF based materials) membrane surfaces was developed. Effects of surface modification on the membranes structure and properties were evaluated.

M3 - Conference Abstract

ER -

Hakalahti M, Hänninen T, Setälä H, Karim Z, Mathew AP, Mautner A et al. Surface modification of nanocellulose membranes using thermoresponsive poly(N-isopropylacrylamide). 2014. Abstract from 4th Dissemination workshop of the Nano4water cluster, Stockholm, Sweden.