Abstract
A constrained free energy model for an interfacial system of interacting layers is derived in the regular solution and Redlich-Kister formalisms. Composition and interfacial energies are solved using a model based on the minimisation of the total free energy of the system with a fixed interfacial area. As example cases iron-oxygen and copper-oxygen surfaces and liquid-liquid metal alloy interfaces are studied.
| Original language | English |
|---|---|
| Pages (from-to) | 736-747 |
| Journal | International Journal of Materials Research |
| Volume | 104 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 2013 |
| MoE publication type | A1 Journal article-refereed |
Keywords
- constrained free energy
- interfacial tension
- metal-oxygen adsorption
- surface tension
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