Synthesis and Characterisation of Optical Sol-gel Waveguide Materials: Master's thesis

Mikko Keränen

Research output: ThesisMaster's thesisTheses

Abstract

Plastics and glasses are materials traditionally used to transmit light in optical data transmission applications. Sol-gel technique takes advantage of the best parts from both materials. It is a technique, where solid organic/inorganic hybrid glass materials can be derived from a liquid phase and can have a wide variety of properties. Target for this thesis was to study sol-gel based passive optical waveguide materials for planar optical applications. Their usefulness in optics has been studied widely, but quite often these materials are not suitable due to high C-H and O-H contents. These bonds and especially O-H bonds cause strong absorption loss at telecommunication wavelength windows, which are around 1310 and 1550 nanometers. Therefore, materials were synthesised to contain these bonds as low amount as possible. Several optical waveguide materials were synthesised within the framework of this thesis. Two of them were optically characterised (refractive indices, birefringences and optical losses) to study their applicability for planar optical applications. Raman technique was employed to study reaction kinetics in one system. In addition, a fluorinated silane precursor was synthesised and characterised by nuclear magnetic resonance (NMR). Fluorination (C-H to C-F) decreases optical losses in sol-gel waveguide materials. Other ways to decrease optical losses are deuteration (C-H to C-D) and chlorination (C-H to C-Cl). Best results were achieved with chlorinated materials. Surface roughness of the planar waveguide structure (slab structure) was 3 nanometers. Optical losses of the waveguide were around 1 dB/cm at 1310 and 1550 nm wavelengths and around 0.4 dB/cm at 830 nm wavelengths. Film thickness for the same material was approximately 4 micrometers.
Original languageEnglish
QualificationMaster Degree
Awarding Institution
  • University of Oulu
Place of PublicationOulu
Publisher
Publication statusPublished - 2003
MoE publication typeG2 Master's thesis, polytechnic Master's thesis

Fingerprint

theses
gels
waveguides
synthesis
optical waveguides
wavelengths
organic solids
chlorination
fluorination
glass
data transmission
silanes
birefringence
telecommunication
micrometers
surface roughness
liquid phases
slabs
reaction kinetics
film thickness

Keywords

  • Sol-gel
  • planar optical waveguide

Cite this

Keränen, Mikko. / Synthesis and Characterisation of Optical Sol-gel Waveguide Materials : Master's thesis. Oulu : University of Oulu, 2003. 84 p.
@phdthesis{af9518c3982e4a2ab2efe17d64424011,
title = "Synthesis and Characterisation of Optical Sol-gel Waveguide Materials: Master's thesis",
abstract = "Plastics and glasses are materials traditionally used to transmit light in optical data transmission applications. Sol-gel technique takes advantage of the best parts from both materials. It is a technique, where solid organic/inorganic hybrid glass materials can be derived from a liquid phase and can have a wide variety of properties. Target for this thesis was to study sol-gel based passive optical waveguide materials for planar optical applications. Their usefulness in optics has been studied widely, but quite often these materials are not suitable due to high C-H and O-H contents. These bonds and especially O-H bonds cause strong absorption loss at telecommunication wavelength windows, which are around 1310 and 1550 nanometers. Therefore, materials were synthesised to contain these bonds as low amount as possible. Several optical waveguide materials were synthesised within the framework of this thesis. Two of them were optically characterised (refractive indices, birefringences and optical losses) to study their applicability for planar optical applications. Raman technique was employed to study reaction kinetics in one system. In addition, a fluorinated silane precursor was synthesised and characterised by nuclear magnetic resonance (NMR). Fluorination (C-H to C-F) decreases optical losses in sol-gel waveguide materials. Other ways to decrease optical losses are deuteration (C-H to C-D) and chlorination (C-H to C-Cl). Best results were achieved with chlorinated materials. Surface roughness of the planar waveguide structure (slab structure) was 3 nanometers. Optical losses of the waveguide were around 1 dB/cm at 1310 and 1550 nm wavelengths and around 0.4 dB/cm at 830 nm wavelengths. Film thickness for the same material was approximately 4 micrometers.",
keywords = "Sol-gel, planar optical waveguide",
author = "Mikko Ker{\"a}nen",
note = "CA: ELE pro gradu Master Thesis University of Oulu, Department of Chemistry 81 p. + app. 3 p.",
year = "2003",
language = "English",
publisher = "University of Oulu",
address = "Finland",
school = "University of Oulu",

}

Keränen, M 2003, 'Synthesis and Characterisation of Optical Sol-gel Waveguide Materials: Master's thesis', Master Degree, University of Oulu, Oulu.

Synthesis and Characterisation of Optical Sol-gel Waveguide Materials : Master's thesis. / Keränen, Mikko.

Oulu : University of Oulu, 2003. 84 p.

Research output: ThesisMaster's thesisTheses

TY - THES

T1 - Synthesis and Characterisation of Optical Sol-gel Waveguide Materials

T2 - Master's thesis

AU - Keränen, Mikko

N1 - CA: ELE pro gradu Master Thesis University of Oulu, Department of Chemistry 81 p. + app. 3 p.

PY - 2003

Y1 - 2003

N2 - Plastics and glasses are materials traditionally used to transmit light in optical data transmission applications. Sol-gel technique takes advantage of the best parts from both materials. It is a technique, where solid organic/inorganic hybrid glass materials can be derived from a liquid phase and can have a wide variety of properties. Target for this thesis was to study sol-gel based passive optical waveguide materials for planar optical applications. Their usefulness in optics has been studied widely, but quite often these materials are not suitable due to high C-H and O-H contents. These bonds and especially O-H bonds cause strong absorption loss at telecommunication wavelength windows, which are around 1310 and 1550 nanometers. Therefore, materials were synthesised to contain these bonds as low amount as possible. Several optical waveguide materials were synthesised within the framework of this thesis. Two of them were optically characterised (refractive indices, birefringences and optical losses) to study their applicability for planar optical applications. Raman technique was employed to study reaction kinetics in one system. In addition, a fluorinated silane precursor was synthesised and characterised by nuclear magnetic resonance (NMR). Fluorination (C-H to C-F) decreases optical losses in sol-gel waveguide materials. Other ways to decrease optical losses are deuteration (C-H to C-D) and chlorination (C-H to C-Cl). Best results were achieved with chlorinated materials. Surface roughness of the planar waveguide structure (slab structure) was 3 nanometers. Optical losses of the waveguide were around 1 dB/cm at 1310 and 1550 nm wavelengths and around 0.4 dB/cm at 830 nm wavelengths. Film thickness for the same material was approximately 4 micrometers.

AB - Plastics and glasses are materials traditionally used to transmit light in optical data transmission applications. Sol-gel technique takes advantage of the best parts from both materials. It is a technique, where solid organic/inorganic hybrid glass materials can be derived from a liquid phase and can have a wide variety of properties. Target for this thesis was to study sol-gel based passive optical waveguide materials for planar optical applications. Their usefulness in optics has been studied widely, but quite often these materials are not suitable due to high C-H and O-H contents. These bonds and especially O-H bonds cause strong absorption loss at telecommunication wavelength windows, which are around 1310 and 1550 nanometers. Therefore, materials were synthesised to contain these bonds as low amount as possible. Several optical waveguide materials were synthesised within the framework of this thesis. Two of them were optically characterised (refractive indices, birefringences and optical losses) to study their applicability for planar optical applications. Raman technique was employed to study reaction kinetics in one system. In addition, a fluorinated silane precursor was synthesised and characterised by nuclear magnetic resonance (NMR). Fluorination (C-H to C-F) decreases optical losses in sol-gel waveguide materials. Other ways to decrease optical losses are deuteration (C-H to C-D) and chlorination (C-H to C-Cl). Best results were achieved with chlorinated materials. Surface roughness of the planar waveguide structure (slab structure) was 3 nanometers. Optical losses of the waveguide were around 1 dB/cm at 1310 and 1550 nm wavelengths and around 0.4 dB/cm at 830 nm wavelengths. Film thickness for the same material was approximately 4 micrometers.

KW - Sol-gel

KW - planar optical waveguide

M3 - Master's thesis

PB - University of Oulu

CY - Oulu

ER -