Abstract
| Original language | English |
|---|---|
| Pages (from-to) | 1591-1598 |
| Number of pages | 8 |
| Journal | European Journal of Organic Chemistry |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 2013 |
| MoE publication type | A1 Journal article-refereed |
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Synthesis and characterization of the O-alkylation products of resorcinarene. / Salorinne, K.; Nauha, E.; Nissinen, M.; Ropponen, Jarmo (Corresponding Author).
In: European Journal of Organic Chemistry, No. 8, 2013, p. 1591-1598.Research output: Contribution to journal › Article › Scientific › peer-review
TY - JOUR
T1 - Synthesis and characterization of the O-alkylation products of resorcinarene
AU - Salorinne, K.
AU - Nauha, E.
AU - Nissinen, M.
AU - Ropponen, Jarmo
PY - 2013
Y1 - 2013
N2 - O‐Substitution reactions of tetramethoxyresorcinarene with alkyl halides produced a variety of partially O‐alkylated resorcinarene derivatives with terminal alkyne functionality. The degree of alkylation was affected by the reactivity of the alkylating halide used. NMR spectroscopy proved to be an ideal tool for analyzing the complex reaction mixtures and the isolated products based on the symmetry and degree of alkylation of the resorcinarene derivatives. Single‐crystal X‐ray diffraction studies furthermore showed diversity in the self‐assembly of the various O‐alkylation products that was greatly affected by the degree of alkylation, as well as the nature of the alkyne moiety.
AB - O‐Substitution reactions of tetramethoxyresorcinarene with alkyl halides produced a variety of partially O‐alkylated resorcinarene derivatives with terminal alkyne functionality. The degree of alkylation was affected by the reactivity of the alkylating halide used. NMR spectroscopy proved to be an ideal tool for analyzing the complex reaction mixtures and the isolated products based on the symmetry and degree of alkylation of the resorcinarene derivatives. Single‐crystal X‐ray diffraction studies furthermore showed diversity in the self‐assembly of the various O‐alkylation products that was greatly affected by the degree of alkylation, as well as the nature of the alkyne moiety.
U2 - 10.1002/ejoc.201201509
DO - 10.1002/ejoc.201201509
M3 - Article
SP - 1591
EP - 1598
JO - European Journal of Organic Chemistry
JF - European Journal of Organic Chemistry
SN - 1434-193X
IS - 8
ER -