Synthesis and characterization of the O-alkylation products of resorcinarene

K. Salorinne, E. Nauha, M. Nissinen, Jarmo Ropponen (Corresponding Author)

Research output: Contribution to journalArticleScientificpeer-review

10 Citations (Scopus)

Abstract

O‐Substitution reactions of tetramethoxyresorcinarene with alkyl halides produced a variety of partially O‐alkylated resorcinarene derivatives with terminal alkyne functionality. The degree of alkylation was affected by the reactivity of the alkylating halide used. NMR spectroscopy proved to be an ideal tool for analyzing the complex reaction mixtures and the isolated products based on the symmetry and degree of alkylation of the resorcinarene derivatives. Single‐crystal X‐ray diffraction studies furthermore showed diversity in the self‐assembly of the various O‐alkylation products that was greatly affected by the degree of alkylation, as well as the nature of the alkyne moiety.
Original languageEnglish
Pages (from-to)1591-1598
Number of pages8
JournalEuropean Journal of Organic Chemistry
Issue number8
DOIs
Publication statusPublished - 2013
MoE publication typeA1 Journal article-refereed

Fingerprint Dive into the research topics of 'Synthesis and characterization of the <i>O</i>-alkylation products of resorcinarene'. Together they form a unique fingerprint.

  • Cite this