Synthesis and performance of alkyd-acrylic hybrid binders

Nina Heiskanen (Corresponding Author), Saila Jämsä, Leena Paajanen, Salme Koskimies

Research output: Contribution to journalArticleScientificpeer-review

20 Citations (Scopus)

Abstract

Preparation and properties of alkyd–acrylic hybrids have been studied. Hybrids with different alkyd–acrylic ratios and acrylic parts were prepared via free radical polymerization of acrylic monomers in a presence of an unsaturated alkyd resin using emulsion polymerization technique. The binders were characterized according to their solid content, conversion, viscosity, pH and particle size. Evidence on formation of true copolymer was obtained via NMR spectroscopy and molecular weight and glass transition temperature measurements, as well as via performance studies. The performance evaluation was focused on investigation of drying, penetration and water repellency ability, as well as on film formation and surface topography studies. The binders were compared to references of an alkyd emulsion, acrylic latex and a blend made of them. The results showed that alkyd–acrylic hybrids with synergistic and improved properties can be prepared.
Original languageEnglish
Pages (from-to)329-338
JournalProgress in Organic Coatings
Volume67
Issue number3
DOIs
Publication statusPublished - 2010
MoE publication typeA1 Journal article-refereed

Fingerprint

Acrylics
Binders
Alkyd resins
Acrylic monomers
Emulsion polymerization
Latex
Surface topography
Free radical polymerization
Emulsions
Latexes
Temperature measurement
Nuclear magnetic resonance spectroscopy
Drying
Copolymers
Molecular weight
Particle size
Viscosity
Water
Glass transition temperature

Keywords

  • alkyd
  • acrylic
  • hybrid
  • preparation
  • coating
  • performance

Cite this

Heiskanen, Nina ; Jämsä, Saila ; Paajanen, Leena ; Koskimies, Salme. / Synthesis and performance of alkyd-acrylic hybrid binders. In: Progress in Organic Coatings. 2010 ; Vol. 67, No. 3. pp. 329-338.
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Heiskanen, N, Jämsä, S, Paajanen, L & Koskimies, S 2010, 'Synthesis and performance of alkyd-acrylic hybrid binders', Progress in Organic Coatings, vol. 67, no. 3, pp. 329-338. https://doi.org/10.1016/j.porgcoat.2009.10.025

Synthesis and performance of alkyd-acrylic hybrid binders. / Heiskanen, Nina (Corresponding Author); Jämsä, Saila; Paajanen, Leena; Koskimies, Salme.

In: Progress in Organic Coatings, Vol. 67, No. 3, 2010, p. 329-338.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - Synthesis and performance of alkyd-acrylic hybrid binders

AU - Heiskanen, Nina

AU - Jämsä, Saila

AU - Paajanen, Leena

AU - Koskimies, Salme

PY - 2010

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AB - Preparation and properties of alkyd–acrylic hybrids have been studied. Hybrids with different alkyd–acrylic ratios and acrylic parts were prepared via free radical polymerization of acrylic monomers in a presence of an unsaturated alkyd resin using emulsion polymerization technique. The binders were characterized according to their solid content, conversion, viscosity, pH and particle size. Evidence on formation of true copolymer was obtained via NMR spectroscopy and molecular weight and glass transition temperature measurements, as well as via performance studies. The performance evaluation was focused on investigation of drying, penetration and water repellency ability, as well as on film formation and surface topography studies. The binders were compared to references of an alkyd emulsion, acrylic latex and a blend made of them. The results showed that alkyd–acrylic hybrids with synergistic and improved properties can be prepared.

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KW - acrylic

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KW - coating

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