The formation of soluble Pb(IV) and Pb(II) species in the reactions of the PbSO4/PbO2 electrode

E. Hämeenoja; Timo Laitinen; Göran Sundholm

doi:10.1016/0013-4686(87)87031-7

The formation of soluble Pb(IV) and Pb(II) species in the reactions of the PbSO4/PbO2 electrode

E. Hämeenoja, Timo Laitinen, Göran Sundholm

VTT Technical Research Centre of Finland

Research output: Contribution to journal › Article › Scientific

11 Citations (Scopus)

Abstract

Using a rotating gold ring—lead disc electrode and analysing the deposit on the ring surface with X-ray photoelectron spectroscopy, soluble Pb(IV) species were detected during the anodic reaction of the PbSO4/PbO2 electrode in sulfuric acid.
The Pb(IV) species are not intermediates in the PbO2 formation but result from the chemical solubility of PbO2.
Measurements of soluble Pb(II) proved that the “coup de fouet” commonly observed during the discharge of the lead acid battery is due to the oversaturation of Pb(II) ions.

Original language	English
Pages (from-to)	187-189
Journal	Electrochimica Acta
Volume	32
Issue number	1
DOIs	https://doi.org/10.1016/0013-4686(87)87031-7
Publication status	Published - 1987
MoE publication type	B1 Article in a scientific magazine

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title = "The formation of soluble Pb(IV) and Pb(II) species in the reactions of the PbSO4/PbO2 electrode",

abstract = "Using a rotating gold ring—lead disc electrode and analysing the deposit on the ring surface with X-ray photoelectron spectroscopy, soluble Pb(IV) species were detected during the anodic reaction of the PbSO4/PbO2 electrode in sulfuric acid. The Pb(IV) species are not intermediates in the PbO2 formation but result from the chemical solubility of PbO2. Measurements of soluble Pb(II) proved that the “coup de fouet” commonly observed during the discharge of the lead acid battery is due to the oversaturation of Pb(II) ions.",

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T1 - The formation of soluble Pb(IV) and Pb(II) species in the reactions of the PbSO4/PbO2 electrode

AU - Hämeenoja, E.

AU - Laitinen, Timo

AU - Sundholm, Göran

PY - 1987

Y1 - 1987

N2 - Using a rotating gold ring—lead disc electrode and analysing the deposit on the ring surface with X-ray photoelectron spectroscopy, soluble Pb(IV) species were detected during the anodic reaction of the PbSO4/PbO2 electrode in sulfuric acid. The Pb(IV) species are not intermediates in the PbO2 formation but result from the chemical solubility of PbO2. Measurements of soluble Pb(II) proved that the “coup de fouet” commonly observed during the discharge of the lead acid battery is due to the oversaturation of Pb(II) ions.

AB - Using a rotating gold ring—lead disc electrode and analysing the deposit on the ring surface with X-ray photoelectron spectroscopy, soluble Pb(IV) species were detected during the anodic reaction of the PbSO4/PbO2 electrode in sulfuric acid. The Pb(IV) species are not intermediates in the PbO2 formation but result from the chemical solubility of PbO2. Measurements of soluble Pb(II) proved that the “coup de fouet” commonly observed during the discharge of the lead acid battery is due to the oversaturation of Pb(II) ions.

U2 - 10.1016/0013-4686(87)87031-7

DO - 10.1016/0013-4686(87)87031-7

M3 - Article

SN - 0013-4686

VL - 32

SP - 187

EP - 189

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 1

ER -

The formation of soluble Pb(IV) and Pb(II) species in the reactions of the PbSO4/PbO2 electrode

Abstract

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