The preparation of lignocellulosic aerogels from ionic liquid solutions

Olli Aaltonen (Corresponding Author), Olli Jauhiainen

Research output: Contribution to journalArticleScientificpeer-review

132 Citations (Scopus)

Abstract

Nanofibrillar aerogels were prepared from cellulose, spruce wood and from mixtures of cellulose, lignin and xylan. The lignocellulosic polymers were first dissolved in an ionic liquid and coagulated from solution by adding aqueous ethanol. The obtained gel was washed with ethanol and liquid carbon dioxide and finally dried by releasing the carbon dioxide from the porous structure at supercritical temperature to obtain the aerogel. The bulk densities of the biopolymer aerogels ranged from 25 to 114 g/l and the internal surface areas (BET) from 108 to 539 m2/g depending on the biopolymer mix and on the polymer concentration in the ionic liquid solution. All aerogels were compressible and consisted of nanofibrillar biomaterial network with open-pore structure.
Original languageEnglish
Pages (from-to)125-129
Number of pages5
JournalCarbohydrate Polymers
Volume75
Issue number1
DOIs
Publication statusPublished - 2009
MoE publication typeA1 Journal article-refereed

Fingerprint

Ionic Liquids
Aerogels
Ionic liquids
Biopolymers
Carbon Dioxide
Cellulose
Carbon dioxide
Polymers
Ethanol
Xylans
Lignin
Biocompatible Materials
Pore structure
Biomaterials
Wood
Gels
Liquids
Temperature

Keywords

  • Aerogels
  • Cellulose
  • Lignocellulose
  • Lignin
  • Xylan
  • Critical point drying
  • Supercritical
  • Carbon dioxide
  • Ionic liquids

Cite this

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abstract = "Nanofibrillar aerogels were prepared from cellulose, spruce wood and from mixtures of cellulose, lignin and xylan. The lignocellulosic polymers were first dissolved in an ionic liquid and coagulated from solution by adding aqueous ethanol. The obtained gel was washed with ethanol and liquid carbon dioxide and finally dried by releasing the carbon dioxide from the porous structure at supercritical temperature to obtain the aerogel. The bulk densities of the biopolymer aerogels ranged from 25 to 114 g/l and the internal surface areas (BET) from 108 to 539 m2/g depending on the biopolymer mix and on the polymer concentration in the ionic liquid solution. All aerogels were compressible and consisted of nanofibrillar biomaterial network with open-pore structure.",
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The preparation of lignocellulosic aerogels from ionic liquid solutions. / Aaltonen, Olli (Corresponding Author); Jauhiainen, Olli.

In: Carbohydrate Polymers, Vol. 75, No. 1, 2009, p. 125-129.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - The preparation of lignocellulosic aerogels from ionic liquid solutions

AU - Aaltonen, Olli

AU - Jauhiainen, Olli

PY - 2009

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AB - Nanofibrillar aerogels were prepared from cellulose, spruce wood and from mixtures of cellulose, lignin and xylan. The lignocellulosic polymers were first dissolved in an ionic liquid and coagulated from solution by adding aqueous ethanol. The obtained gel was washed with ethanol and liquid carbon dioxide and finally dried by releasing the carbon dioxide from the porous structure at supercritical temperature to obtain the aerogel. The bulk densities of the biopolymer aerogels ranged from 25 to 114 g/l and the internal surface areas (BET) from 108 to 539 m2/g depending on the biopolymer mix and on the polymer concentration in the ionic liquid solution. All aerogels were compressible and consisted of nanofibrillar biomaterial network with open-pore structure.

KW - Aerogels

KW - Cellulose

KW - Lignocellulose

KW - Lignin

KW - Xylan

KW - Critical point drying

KW - Supercritical

KW - Carbon dioxide

KW - Ionic liquids

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JF - Carbohydrate Polymers

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