The Role of Film Processing in the Large-Area Dielectric Breakdown Performance of Nano-Silica-BOPP Films

Ilkka Rytöluoto, Mikael Ritamäki, Kari Lahti, Mikko Karttunen

Research output: Chapter in Book/Report/Conference proceedingConference article in proceedingsScientificpeer-review

Abstract

This paper summarizes the effects of various compositional, structural and film processing factors on the breakdown behavior of laboratory- and pilot-scale melt-compounded bi-axially oriented polypropylene (BOPP) nanocomposite films with silica fillers. A self-healing multi-breakdown measurement approach has been extensively utilized for large-area breakdown characterization of a large number of material variants from different processing trials. The results suggest that although the optimum level of silica presumably resides at the low fill-fraction range (~1 wt-%), the silica content itself is not the only determining factor, as compounds with equal silica content were found to exhibit large differences in the breakdown properties depending on the compounding and film processing steps. Dispersion quality and filler agglomeration (in both the nm- and µm-scale) appear to be of great importance. Indications of possible interaction between nano-silica and co-stabilizer Irgafos 168 are also presented. Overall, the laboratory- and pilot-scale film processing trials suggest that up-scaling of the polymer nanocomposite production is sensible with traditional melt-blending technology, although further development and optimization of nanocomposite formulations and processing is necessary.
Original languageEnglish
Title of host publicationProceedings of the 24th Nordic Insulation Symposium
Pages63-68
Publication statusPublished - 2015
MoE publication typeA4 Article in a conference publication
Event24th Nordic Insulation Symposium on Materials, Components and Diagnostics, NORD-IS - Copenhagen, Denmark
Duration: 5 Jun 201517 Jun 2015
Conference number: 24

Publication series

Name
Number24
ISSN (Electronic)2535-3969

Conference

Conference24th Nordic Insulation Symposium on Materials, Components and Diagnostics, NORD-IS
Abbreviated titleNORD-IS
CountryDenmark
CityCopenhagen
Period5/06/1517/06/15

Fingerprint

Polypropylenes
Electric breakdown
Silicon Dioxide
Processing
Fillers
Nanocomposites
Nanocomposite films
Polymers
Agglomeration

Keywords

  • Bi-axially oriented polypropylene (BOPP)
  • nanocomposite
  • multi-breakdown

Cite this

Rytöluoto, I., Ritamäki, M., Lahti, K., & Karttunen, M. (2015). The Role of Film Processing in the Large-Area Dielectric Breakdown Performance of Nano-Silica-BOPP Films. In Proceedings of the 24th Nordic Insulation Symposium (pp. 63-68)
Rytöluoto, Ilkka ; Ritamäki, Mikael ; Lahti, Kari ; Karttunen, Mikko. / The Role of Film Processing in the Large-Area Dielectric Breakdown Performance of Nano-Silica-BOPP Films. Proceedings of the 24th Nordic Insulation Symposium. 2015. pp. 63-68
@inproceedings{3248a66b47ae47fabe73f2db5e6a71ff,
title = "The Role of Film Processing in the Large-Area Dielectric Breakdown Performance of Nano-Silica-BOPP Films",
abstract = "This paper summarizes the effects of various compositional, structural and film processing factors on the breakdown behavior of laboratory- and pilot-scale melt-compounded bi-axially oriented polypropylene (BOPP) nanocomposite films with silica fillers. A self-healing multi-breakdown measurement approach has been extensively utilized for large-area breakdown characterization of a large number of material variants from different processing trials. The results suggest that although the optimum level of silica presumably resides at the low fill-fraction range (~1 wt-{\%}), the silica content itself is not the only determining factor, as compounds with equal silica content were found to exhibit large differences in the breakdown properties depending on the compounding and film processing steps. Dispersion quality and filler agglomeration (in both the nm- and µm-scale) appear to be of great importance. Indications of possible interaction between nano-silica and co-stabilizer Irgafos 168 are also presented. Overall, the laboratory- and pilot-scale film processing trials suggest that up-scaling of the polymer nanocomposite production is sensible with traditional melt-blending technology, although further development and optimization of nanocomposite formulations and processing is necessary.",
keywords = "Bi-axially oriented polypropylene (BOPP), nanocomposite, multi-breakdown",
author = "Ilkka Ryt{\"o}luoto and Mikael Ritam{\"a}ki and Kari Lahti and Mikko Karttunen",
year = "2015",
language = "English",
number = "24",
pages = "63--68",
booktitle = "Proceedings of the 24th Nordic Insulation Symposium",

}

Rytöluoto, I, Ritamäki, M, Lahti, K & Karttunen, M 2015, The Role of Film Processing in the Large-Area Dielectric Breakdown Performance of Nano-Silica-BOPP Films. in Proceedings of the 24th Nordic Insulation Symposium. pp. 63-68, 24th Nordic Insulation Symposium on Materials, Components and Diagnostics, NORD-IS, Copenhagen, Denmark, 5/06/15.

The Role of Film Processing in the Large-Area Dielectric Breakdown Performance of Nano-Silica-BOPP Films. / Rytöluoto, Ilkka; Ritamäki, Mikael; Lahti, Kari; Karttunen, Mikko.

Proceedings of the 24th Nordic Insulation Symposium. 2015. p. 63-68.

Research output: Chapter in Book/Report/Conference proceedingConference article in proceedingsScientificpeer-review

TY - GEN

T1 - The Role of Film Processing in the Large-Area Dielectric Breakdown Performance of Nano-Silica-BOPP Films

AU - Rytöluoto, Ilkka

AU - Ritamäki, Mikael

AU - Lahti, Kari

AU - Karttunen, Mikko

PY - 2015

Y1 - 2015

N2 - This paper summarizes the effects of various compositional, structural and film processing factors on the breakdown behavior of laboratory- and pilot-scale melt-compounded bi-axially oriented polypropylene (BOPP) nanocomposite films with silica fillers. A self-healing multi-breakdown measurement approach has been extensively utilized for large-area breakdown characterization of a large number of material variants from different processing trials. The results suggest that although the optimum level of silica presumably resides at the low fill-fraction range (~1 wt-%), the silica content itself is not the only determining factor, as compounds with equal silica content were found to exhibit large differences in the breakdown properties depending on the compounding and film processing steps. Dispersion quality and filler agglomeration (in both the nm- and µm-scale) appear to be of great importance. Indications of possible interaction between nano-silica and co-stabilizer Irgafos 168 are also presented. Overall, the laboratory- and pilot-scale film processing trials suggest that up-scaling of the polymer nanocomposite production is sensible with traditional melt-blending technology, although further development and optimization of nanocomposite formulations and processing is necessary.

AB - This paper summarizes the effects of various compositional, structural and film processing factors on the breakdown behavior of laboratory- and pilot-scale melt-compounded bi-axially oriented polypropylene (BOPP) nanocomposite films with silica fillers. A self-healing multi-breakdown measurement approach has been extensively utilized for large-area breakdown characterization of a large number of material variants from different processing trials. The results suggest that although the optimum level of silica presumably resides at the low fill-fraction range (~1 wt-%), the silica content itself is not the only determining factor, as compounds with equal silica content were found to exhibit large differences in the breakdown properties depending on the compounding and film processing steps. Dispersion quality and filler agglomeration (in both the nm- and µm-scale) appear to be of great importance. Indications of possible interaction between nano-silica and co-stabilizer Irgafos 168 are also presented. Overall, the laboratory- and pilot-scale film processing trials suggest that up-scaling of the polymer nanocomposite production is sensible with traditional melt-blending technology, although further development and optimization of nanocomposite formulations and processing is necessary.

KW - Bi-axially oriented polypropylene (BOPP)

KW - nanocomposite

KW - multi-breakdown

M3 - Conference article in proceedings

SP - 63

EP - 68

BT - Proceedings of the 24th Nordic Insulation Symposium

ER -

Rytöluoto I, Ritamäki M, Lahti K, Karttunen M. The Role of Film Processing in the Large-Area Dielectric Breakdown Performance of Nano-Silica-BOPP Films. In Proceedings of the 24th Nordic Insulation Symposium. 2015. p. 63-68