The role of ink component diffusion during absorption into inkjet coatings

Taina Lamminmäki, John Kettle, Pasi Puukko, C. J. Ridgway, P.A.C. Gane

Research output: Chapter in Book/Report/Conference proceedingConference article in proceedingsScientificpeer-review

3 Citations (Scopus)

Abstract

Inkjet coatings usually contain specialty pigments with a high specific surface area and binders which provide high binding force. The final coating structure has a high pore volume and it contains a high frequency of fine diameter pores together with large pore volume capacity. During the inkjet ink absorption process, the capillary and permeation flow drives the liquid into the coating structure and controls volume flow, respectively. However, the role of diffusion within the timescale of the inkjet ink imbibition process has not been studied widely. The aim of this work is to clarify the interactive role of the porous structure and the coexistent swelling of binder during the liquid imbibition, with special attention to the fixation of dye and its distribution. The impact of polarity of the vehicle was studied using compressed pigment and formulation tablets, recording the liquid imbibition dynamic. Our results show that at the beginning of liquid uptake, at times less than 2 s, the small pores play the dominant role in respect to the ink vehicle imbibition. Simultaneously, water molecules on contact diffuse into and within hydrophilic binder, exemplified by polyvinyl alcohol, causing binder swelling. The swelling affects the number of active small pores and reduces the diameter of remaining pores, slowing the capillary flow as a function of time. At longer timescale, therefore, drainage by permeation flow wins over the capillary driven liquid imbibition. In the fixing of dye molecules, the electrostatic interactions are dominant. The type and modification of binder can affect the chemical groups to which the colorants can fix. On the other hand, the binder properties influence where the dye can physically go and thus where the colorants will finally locate. Polymer swelling acts to open the polymer network to colorant diffusion, such that the colorants can also transfer into the polymer network as a secondary process.
Original languageEnglish
Title of host publicationTAPPI 11th Advanced Coating Fundamentals Symposium
Subtitle of host publicationThe Latest Advances in Coating Research and Development. Munich, Germany, 11-13 Oct. 2010
PublisherTAPPI Press
Pages195-214
ISBN (Print)978-159510203-4
Publication statusPublished - 2010
MoE publication typeA4 Article in a conference publication

Fingerprint

Ink
Binders
Coatings
Swelling
Liquids
Polymers
Coloring Agents
Pigments
Permeation
Capillary flow
Polyvinyl Alcohol
Molecules
Coulomb interactions
Specific surface area
Tablets
Drainage
Water

Keywords

  • diffusion
  • absorption
  • porosity
  • permeability
  • ink penetration
  • ink dye adsorption
  • inkjet printing

Cite this

Lamminmäki, T., Kettle, J., Puukko, P., Ridgway, C. J., & Gane, P. A. C. (2010). The role of ink component diffusion during absorption into inkjet coatings. In TAPPI 11th Advanced Coating Fundamentals Symposium: The Latest Advances in Coating Research and Development. Munich, Germany, 11-13 Oct. 2010 (pp. 195-214). TAPPI Press.
Lamminmäki, Taina ; Kettle, John ; Puukko, Pasi ; Ridgway, C. J. ; Gane, P.A.C. / The role of ink component diffusion during absorption into inkjet coatings. TAPPI 11th Advanced Coating Fundamentals Symposium: The Latest Advances in Coating Research and Development. Munich, Germany, 11-13 Oct. 2010. TAPPI Press, 2010. pp. 195-214
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Lamminmäki, T, Kettle, J, Puukko, P, Ridgway, CJ & Gane, PAC 2010, The role of ink component diffusion during absorption into inkjet coatings. in TAPPI 11th Advanced Coating Fundamentals Symposium: The Latest Advances in Coating Research and Development. Munich, Germany, 11-13 Oct. 2010. TAPPI Press, pp. 195-214.

The role of ink component diffusion during absorption into inkjet coatings. / Lamminmäki, Taina; Kettle, John; Puukko, Pasi; Ridgway, C. J.; Gane, P.A.C.

TAPPI 11th Advanced Coating Fundamentals Symposium: The Latest Advances in Coating Research and Development. Munich, Germany, 11-13 Oct. 2010. TAPPI Press, 2010. p. 195-214.

Research output: Chapter in Book/Report/Conference proceedingConference article in proceedingsScientificpeer-review

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AU - Kettle, John

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N2 - Inkjet coatings usually contain specialty pigments with a high specific surface area and binders which provide high binding force. The final coating structure has a high pore volume and it contains a high frequency of fine diameter pores together with large pore volume capacity. During the inkjet ink absorption process, the capillary and permeation flow drives the liquid into the coating structure and controls volume flow, respectively. However, the role of diffusion within the timescale of the inkjet ink imbibition process has not been studied widely. The aim of this work is to clarify the interactive role of the porous structure and the coexistent swelling of binder during the liquid imbibition, with special attention to the fixation of dye and its distribution. The impact of polarity of the vehicle was studied using compressed pigment and formulation tablets, recording the liquid imbibition dynamic. Our results show that at the beginning of liquid uptake, at times less than 2 s, the small pores play the dominant role in respect to the ink vehicle imbibition. Simultaneously, water molecules on contact diffuse into and within hydrophilic binder, exemplified by polyvinyl alcohol, causing binder swelling. The swelling affects the number of active small pores and reduces the diameter of remaining pores, slowing the capillary flow as a function of time. At longer timescale, therefore, drainage by permeation flow wins over the capillary driven liquid imbibition. In the fixing of dye molecules, the electrostatic interactions are dominant. The type and modification of binder can affect the chemical groups to which the colorants can fix. On the other hand, the binder properties influence where the dye can physically go and thus where the colorants will finally locate. Polymer swelling acts to open the polymer network to colorant diffusion, such that the colorants can also transfer into the polymer network as a secondary process.

AB - Inkjet coatings usually contain specialty pigments with a high specific surface area and binders which provide high binding force. The final coating structure has a high pore volume and it contains a high frequency of fine diameter pores together with large pore volume capacity. During the inkjet ink absorption process, the capillary and permeation flow drives the liquid into the coating structure and controls volume flow, respectively. However, the role of diffusion within the timescale of the inkjet ink imbibition process has not been studied widely. The aim of this work is to clarify the interactive role of the porous structure and the coexistent swelling of binder during the liquid imbibition, with special attention to the fixation of dye and its distribution. The impact of polarity of the vehicle was studied using compressed pigment and formulation tablets, recording the liquid imbibition dynamic. Our results show that at the beginning of liquid uptake, at times less than 2 s, the small pores play the dominant role in respect to the ink vehicle imbibition. Simultaneously, water molecules on contact diffuse into and within hydrophilic binder, exemplified by polyvinyl alcohol, causing binder swelling. The swelling affects the number of active small pores and reduces the diameter of remaining pores, slowing the capillary flow as a function of time. At longer timescale, therefore, drainage by permeation flow wins over the capillary driven liquid imbibition. In the fixing of dye molecules, the electrostatic interactions are dominant. The type and modification of binder can affect the chemical groups to which the colorants can fix. On the other hand, the binder properties influence where the dye can physically go and thus where the colorants will finally locate. Polymer swelling acts to open the polymer network to colorant diffusion, such that the colorants can also transfer into the polymer network as a secondary process.

KW - diffusion

KW - absorption

KW - porosity

KW - permeability

KW - ink penetration

KW - ink dye adsorption

KW - inkjet printing

M3 - Conference article in proceedings

SN - 978-159510203-4

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BT - TAPPI 11th Advanced Coating Fundamentals Symposium

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Lamminmäki T, Kettle J, Puukko P, Ridgway CJ, Gane PAC. The role of ink component diffusion during absorption into inkjet coatings. In TAPPI 11th Advanced Coating Fundamentals Symposium: The Latest Advances in Coating Research and Development. Munich, Germany, 11-13 Oct. 2010. TAPPI Press. 2010. p. 195-214