Abstract
Original language | English |
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Pages (from-to) | 109-115 |
Number of pages | 6 |
Journal | Jurnal Teknologi |
Volume | 67 |
Issue number | 3 |
DOIs | |
Publication status | Published - 2014 |
MoE publication type | A1 Journal article-refereed |
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Thermodynamic analysis of glycerol steam reforming to ethylene. / Zakaria, Z Y; Linnekoski, Juha; Amin, N A S.
In: Jurnal Teknologi, Vol. 67, No. 3, 2014, p. 109-115.Research output: Contribution to journal › Article › Scientific › peer-review
TY - JOUR
T1 - Thermodynamic analysis of glycerol steam reforming to ethylene
AU - Zakaria, Z Y
AU - Linnekoski, Juha
AU - Amin, N A S
PY - 2014
Y1 - 2014
N2 - Thermodynamic equilibrium analysis of glycerol steam reforming to ethylene has been investigated based on the total Gibbs free energy minimization method. Equilibrium product compositions for glycerol steam reforming were determined for temperatures ranging from 573-1273 K and GWR (glycerol/water ratio) 1:12 to 2:1 at 1 bar pressure. The objectives of this study are to identify the thermodynamic range of the process operation and study the variation of product distribution. It was found that the formation of ethylene was difficult to accomplish and the amount of ethylene produced is very small. The formation of coke, which will poison the catalyst, could be suppressed at higher operating temperature. The thermoneutral temperature of the process was found to increase with GWR. Other means to encourage the formation of more ethylene is required
AB - Thermodynamic equilibrium analysis of glycerol steam reforming to ethylene has been investigated based on the total Gibbs free energy minimization method. Equilibrium product compositions for glycerol steam reforming were determined for temperatures ranging from 573-1273 K and GWR (glycerol/water ratio) 1:12 to 2:1 at 1 bar pressure. The objectives of this study are to identify the thermodynamic range of the process operation and study the variation of product distribution. It was found that the formation of ethylene was difficult to accomplish and the amount of ethylene produced is very small. The formation of coke, which will poison the catalyst, could be suppressed at higher operating temperature. The thermoneutral temperature of the process was found to increase with GWR. Other means to encourage the formation of more ethylene is required
U2 - 10.11113/jt.v67.2773
DO - 10.11113/jt.v67.2773
M3 - Article
VL - 67
SP - 109
EP - 115
JO - Jurnal Teknologi
JF - Jurnal Teknologi
SN - 0127-9696
IS - 3
ER -