Thickness measurement of thin polymer films by total internal reflection Raman and attenuated total reflection infrared spectroscopy

A. O. Kivioja, Anna-Stiina Jääskeläinen (Corresponding Author), V. Ahtee, T. Vuorinen

Research output: Contribution to journalArticleScientificpeer-review

10 Citations (Scopus)

Abstract

For the first time total internal reflection (TIR) Raman spectroscopy was utilized for thickness measurements of thin isotropic polystyrene films on polypropylene substrate. In the presented method, the band intensity ratios of polystyrene to polypropylene were defined from the spectra, and the film thicknesses in a range from 50 nm to 350 nm were calculated mathematically from these ratios. The quantitativeness of the method was validated by applying the same principle to attenuated total reflection infrared (ATR-IR) spectroscopy and comparing the results to values obtained by ellipsometry and a spin-coating model. The results showed that the novel and non-invasive TIR Raman method reveals the film thickness quantitatively, and the method is applicable for thin films on soft substrates with similar refractive indices.
Original languageEnglish
Pages (from-to)1-9
Number of pages9
JournalVibrational Spectroscopy
Volume61
Issue number1
DOIs
Publication statusPublished - 2012
MoE publication typeA1 Journal article-refereed

Fingerprint

Thickness measurement
Polymer films
Infrared spectroscopy
Polypropylenes
Polystyrenes
Thin films
Film thickness
Ellipsometry
Spin coating
Substrates
Raman spectroscopy
Refractive index

Keywords

  • Total internal reflection Raman spectroscopy
  • thin film
  • attenuated total reflection infrared spectroscopy
  • ellipsometry
  • thickness
  • ultra-thin film

Cite this

Kivioja, A. O. ; Jääskeläinen, Anna-Stiina ; Ahtee, V. ; Vuorinen, T. / Thickness measurement of thin polymer films by total internal reflection Raman and attenuated total reflection infrared spectroscopy. In: Vibrational Spectroscopy. 2012 ; Vol. 61, No. 1. pp. 1-9.
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Thickness measurement of thin polymer films by total internal reflection Raman and attenuated total reflection infrared spectroscopy. / Kivioja, A. O.; Jääskeläinen, Anna-Stiina (Corresponding Author); Ahtee, V.; Vuorinen, T.

In: Vibrational Spectroscopy, Vol. 61, No. 1, 2012, p. 1-9.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - Thickness measurement of thin polymer films by total internal reflection Raman and attenuated total reflection infrared spectroscopy

AU - Kivioja, A. O.

AU - Jääskeläinen, Anna-Stiina

AU - Ahtee, V.

AU - Vuorinen, T.

PY - 2012

Y1 - 2012

N2 - For the first time total internal reflection (TIR) Raman spectroscopy was utilized for thickness measurements of thin isotropic polystyrene films on polypropylene substrate. In the presented method, the band intensity ratios of polystyrene to polypropylene were defined from the spectra, and the film thicknesses in a range from 50 nm to 350 nm were calculated mathematically from these ratios. The quantitativeness of the method was validated by applying the same principle to attenuated total reflection infrared (ATR-IR) spectroscopy and comparing the results to values obtained by ellipsometry and a spin-coating model. The results showed that the novel and non-invasive TIR Raman method reveals the film thickness quantitatively, and the method is applicable for thin films on soft substrates with similar refractive indices.

AB - For the first time total internal reflection (TIR) Raman spectroscopy was utilized for thickness measurements of thin isotropic polystyrene films on polypropylene substrate. In the presented method, the band intensity ratios of polystyrene to polypropylene were defined from the spectra, and the film thicknesses in a range from 50 nm to 350 nm were calculated mathematically from these ratios. The quantitativeness of the method was validated by applying the same principle to attenuated total reflection infrared (ATR-IR) spectroscopy and comparing the results to values obtained by ellipsometry and a spin-coating model. The results showed that the novel and non-invasive TIR Raman method reveals the film thickness quantitatively, and the method is applicable for thin films on soft substrates with similar refractive indices.

KW - Total internal reflection Raman spectroscopy

KW - thin film

KW - attenuated total reflection infrared spectroscopy

KW - ellipsometry

KW - thickness

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