ToF-SIMS 3d analysis of thin films deposited in high aspect ratio structures via atomic layer deposition and chemical vapor deposition

Alireza M. Kia (Corresponding Author), Nora Haufe, Sajjad Esmaeili, Clemens Mart, Mikko Utriainen, Riikka L. Puurunen, Wenke Weinreich

Research output: Contribution to journalArticleScientificpeer-review

2 Citations (Scopus)

Abstract

For the analysis of thin films, with high aspect ratio (HAR) structures, time-of-flight secondary ion mass spectrometry (ToF-SIMS) overcomes several challenges in comparison to other frequently used techniques such as electron microscopy. The research presented herein focuses on two different kinds of HAR structures that represent different semiconductor technologies. In the first study, ToF-SIMS is used to illustrate cobalt seed layer corrosion by the copper electrolyte within the large through-silicon-vias (TSVs) before and after copper electroplating. However, due to the sample’s surface topography, ToF-SIMS analysis proved to be difficult due to the geometrical shadowing effects. Henceforth, in the second study, we introduce a new test platform to eliminate the difficulties with the HAR structures, and again, use ToF-SIMS for elemental analysis. We use data image slicing of 3D ToF-SIMS analysis combined with lateral HAR test chips (PillarHall™) to study the uniformity of silicon dopant concentration in atomic layer deposited (ALD) HfO2 thin films.

Original languageEnglish
Article number1035
JournalNanomaterials
Volume9
Issue number7
DOIs
Publication statusPublished - Jul 2019
MoE publication typeA1 Journal article-refereed

Fingerprint

Atomic layer deposition
Secondary ion mass spectrometry
Aspect ratio
Chemical vapor deposition
Thin films
Silicon
Copper
Electroplating
Surface topography
Cobalt
Electron microscopy
Electrolytes
Seed
Doping (additives)
Corrosion
Semiconductor materials
Chemical analysis

Keywords

  • Compositional depth profiling
  • High aspect ratio (HAR) structures
  • Lateral high aspect ratio (LHAR)
  • Silicon doped hafnium oxide (HSO) ALD deposition
  • ToF-SIMS 3D imaging
  • ToF-SIMS analysis

Cite this

Kia, Alireza M. ; Haufe, Nora ; Esmaeili, Sajjad ; Mart, Clemens ; Utriainen, Mikko ; Puurunen, Riikka L. ; Weinreich, Wenke. / ToF-SIMS 3d analysis of thin films deposited in high aspect ratio structures via atomic layer deposition and chemical vapor deposition. In: Nanomaterials. 2019 ; Vol. 9, No. 7.
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ToF-SIMS 3d analysis of thin films deposited in high aspect ratio structures via atomic layer deposition and chemical vapor deposition. / Kia, Alireza M. (Corresponding Author); Haufe, Nora; Esmaeili, Sajjad; Mart, Clemens; Utriainen, Mikko; Puurunen, Riikka L.; Weinreich, Wenke.

In: Nanomaterials, Vol. 9, No. 7, 1035, 07.2019.

Research output: Contribution to journalArticleScientificpeer-review

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