TPR and FT-IR studies on carbonyl cluster derived Co-Rh/SiO2 catalysts

Jari Kiviaho (Corresponding Author), Marita Niemelä, Yoshio Morioka, Kirsi Kataja

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Abstract

he decarbonylation of Co4−nRhn(CO)12/SiO2 and (Co4(CO)12 +Rh4(CO)12)/SiO2 catalysts was studied by temperature programmed reduction (TPR) and in-situ diffuse reflectance FT-IR techniques. Special attention was paid to the effect of the decomposition atmosphere on the supported catalysts. The temperature of decarbonylation depended on the precursor, and the CO desorption peak maxima during the TPR were as follows: Co2Rh2(CO)12 = 123°C, Co3Rh(CO)12 = 125°C, (Co4(CO)12 + Rh4(CO)12) = 135°C, Co4(CO)12 = 137°C and Rh4(CO)12 = 178°C. The CO desorption was greatest for Co4(CO)12, and less and similar for other catalysts. Thus, from rhodium containing catalysts less CO was desorbed at elevated temperatures indicating a stronger interaction of rhodium than of cobalt with the support. Correspondingly, according to FT-IR measurements, the stability of the tetranuclear carbonyls supported on silica decreased in the order Co4(CO)12 > bimetallic carbonyls > Rh4(CO)12 at room temperature.
Original languageEnglish
Pages (from-to)93-109
Number of pages17
JournalApplied Catalysis A: General
Volume144
Issue number1-2
DOIs
Publication statusPublished - 1996
MoE publication typeA1 Journal article-refereed

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Catalysts
Rhodium
Desorption
Temperature
Cobalt
Catalyst supports
Silicon Dioxide
Silica
Decomposition

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Kiviaho, Jari ; Niemelä, Marita ; Morioka, Yoshio ; Kataja, Kirsi. / TPR and FT-IR studies on carbonyl cluster derived Co-Rh/SiO2 catalysts. In: Applied Catalysis A: General. 1996 ; Vol. 144, No. 1-2. pp. 93-109.
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title = "TPR and FT-IR studies on carbonyl cluster derived Co-Rh/SiO2 catalysts",
abstract = "he decarbonylation of Co4−nRhn(CO)12/SiO2 and (Co4(CO)12 +Rh4(CO)12)/SiO2 catalysts was studied by temperature programmed reduction (TPR) and in-situ diffuse reflectance FT-IR techniques. Special attention was paid to the effect of the decomposition atmosphere on the supported catalysts. The temperature of decarbonylation depended on the precursor, and the CO desorption peak maxima during the TPR were as follows: Co2Rh2(CO)12 = 123°C, Co3Rh(CO)12 = 125°C, (Co4(CO)12 + Rh4(CO)12) = 135°C, Co4(CO)12 = 137°C and Rh4(CO)12 = 178°C. The CO desorption was greatest for Co4(CO)12, and less and similar for other catalysts. Thus, from rhodium containing catalysts less CO was desorbed at elevated temperatures indicating a stronger interaction of rhodium than of cobalt with the support. Correspondingly, according to FT-IR measurements, the stability of the tetranuclear carbonyls supported on silica decreased in the order Co4(CO)12 > bimetallic carbonyls > Rh4(CO)12 at room temperature.",
author = "Jari Kiviaho and Marita Niemel{\"a} and Yoshio Morioka and Kirsi Kataja",
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TPR and FT-IR studies on carbonyl cluster derived Co-Rh/SiO2 catalysts. / Kiviaho, Jari (Corresponding Author); Niemelä, Marita; Morioka, Yoshio; Kataja, Kirsi.

In: Applied Catalysis A: General, Vol. 144, No. 1-2, 1996, p. 93-109.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - TPR and FT-IR studies on carbonyl cluster derived Co-Rh/SiO2 catalysts

AU - Kiviaho, Jari

AU - Niemelä, Marita

AU - Morioka, Yoshio

AU - Kataja, Kirsi

PY - 1996

Y1 - 1996

N2 - he decarbonylation of Co4−nRhn(CO)12/SiO2 and (Co4(CO)12 +Rh4(CO)12)/SiO2 catalysts was studied by temperature programmed reduction (TPR) and in-situ diffuse reflectance FT-IR techniques. Special attention was paid to the effect of the decomposition atmosphere on the supported catalysts. The temperature of decarbonylation depended on the precursor, and the CO desorption peak maxima during the TPR were as follows: Co2Rh2(CO)12 = 123°C, Co3Rh(CO)12 = 125°C, (Co4(CO)12 + Rh4(CO)12) = 135°C, Co4(CO)12 = 137°C and Rh4(CO)12 = 178°C. The CO desorption was greatest for Co4(CO)12, and less and similar for other catalysts. Thus, from rhodium containing catalysts less CO was desorbed at elevated temperatures indicating a stronger interaction of rhodium than of cobalt with the support. Correspondingly, according to FT-IR measurements, the stability of the tetranuclear carbonyls supported on silica decreased in the order Co4(CO)12 > bimetallic carbonyls > Rh4(CO)12 at room temperature.

AB - he decarbonylation of Co4−nRhn(CO)12/SiO2 and (Co4(CO)12 +Rh4(CO)12)/SiO2 catalysts was studied by temperature programmed reduction (TPR) and in-situ diffuse reflectance FT-IR techniques. Special attention was paid to the effect of the decomposition atmosphere on the supported catalysts. The temperature of decarbonylation depended on the precursor, and the CO desorption peak maxima during the TPR were as follows: Co2Rh2(CO)12 = 123°C, Co3Rh(CO)12 = 125°C, (Co4(CO)12 + Rh4(CO)12) = 135°C, Co4(CO)12 = 137°C and Rh4(CO)12 = 178°C. The CO desorption was greatest for Co4(CO)12, and less and similar for other catalysts. Thus, from rhodium containing catalysts less CO was desorbed at elevated temperatures indicating a stronger interaction of rhodium than of cobalt with the support. Correspondingly, according to FT-IR measurements, the stability of the tetranuclear carbonyls supported on silica decreased in the order Co4(CO)12 > bimetallic carbonyls > Rh4(CO)12 at room temperature.

U2 - 10.1016/0926-860X(96)00126-3

DO - 10.1016/0926-860X(96)00126-3

M3 - Article

VL - 144

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EP - 109

JO - Applied Catalysis A: General

JF - Applied Catalysis A: General

SN - 0926-860X

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