Tungsten silicide formation from sequentially sputtered tungsten and silicon films

Jyrki Molarius, Sami Franssila, Gyözö Drozdy, Jaakko Saarilahti

Research output: Contribution to journalArticleScientificpeer-review

8 Citations (Scopus)

Abstract

As-deposited tungsten silicide films have typically high resistivity and require annealing to lower the resistivity to practical values. Rapid thermal annealing (RTA) has emerged as the main method because impurity diffusion in silicides is extremely fast. In this study we have explored the possibility of reducing the required thermal budget for tungsten silicide annealing by sputtering multilayer W /Si films. In addition to direct technological relevance, multilayer structures offer new insights into silicide formation. We propose a hypothesis "oxygen supply to interface ratio" for explaining why multilayer W /Si structures are beneficial for silicide formation. We have prevented the possible oxygen barrier formation at the W /Si interface by diminishing the oxygen supply by several means: substrate heating during deposition, multiple thin layers, a silicon capping layer and argon purging during RTA. Tetragonal WSi2 is formed at 700°C and no silicon-rich phases are observed. Low-resistivity WSi2 is produced by RTA at 1000°C, 120 s. Sheet resistance values around 3 ω/□ amends the use of tungsten silicide in practical polycide structures. The ultimate resistivity of our WSi2, 30 μω · cm, is among the lowest reported for tungsten silicide, and it is achieved in a very straightforward fashion, using typical production equipment.
Original languageEnglish
Pages (from-to)383-390
JournalApplied Surface Science
Volume53
DOIs
Publication statusPublished - 17 Aug 1991
MoE publication typeA1 Journal article-refereed

Fingerprint

Tungsten
Silicon
Rapid thermal annealing
Oxygen supply
Multilayers
Annealing
Purging
Silicides
Argon
Sheet resistance
Sputtering
Impurities
Oxygen
Heating
Substrates

Keywords

  • Tungsten
  • silicide

Cite this

Molarius, Jyrki ; Franssila, Sami ; Drozdy, Gyözö ; Saarilahti, Jaakko. / Tungsten silicide formation from sequentially sputtered tungsten and silicon films. In: Applied Surface Science. 1991 ; Vol. 53. pp. 383-390.
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abstract = "As-deposited tungsten silicide films have typically high resistivity and require annealing to lower the resistivity to practical values. Rapid thermal annealing (RTA) has emerged as the main method because impurity diffusion in silicides is extremely fast. In this study we have explored the possibility of reducing the required thermal budget for tungsten silicide annealing by sputtering multilayer W /Si films. In addition to direct technological relevance, multilayer structures offer new insights into silicide formation. We propose a hypothesis {"}oxygen supply to interface ratio{"} for explaining why multilayer W /Si structures are beneficial for silicide formation. We have prevented the possible oxygen barrier formation at the W /Si interface by diminishing the oxygen supply by several means: substrate heating during deposition, multiple thin layers, a silicon capping layer and argon purging during RTA. Tetragonal WSi2 is formed at 700°C and no silicon-rich phases are observed. Low-resistivity WSi2 is produced by RTA at 1000°C, 120 s. Sheet resistance values around 3 ω/□ amends the use of tungsten silicide in practical polycide structures. The ultimate resistivity of our WSi2, 30 μω · cm, is among the lowest reported for tungsten silicide, and it is achieved in a very straightforward fashion, using typical production equipment.",
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Tungsten silicide formation from sequentially sputtered tungsten and silicon films. / Molarius, Jyrki; Franssila, Sami; Drozdy, Gyözö; Saarilahti, Jaakko.

In: Applied Surface Science, Vol. 53, 17.08.1991, p. 383-390.

Research output: Contribution to journalArticleScientificpeer-review

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