Understanding the mechanisms of oxygen diffusion through surface functionalized nanocellulose films

Mari Soledad Peresin, Kari Kammiovirta, Harri Heikkinen, Leena-Sisko Johansson, Jari Vartiainen, Harri Setälä, Monika Österberg, Tekla Tammelin

Research output: Contribution to journalArticleScientificpeer-review

10 Citations (Scopus)

Abstract

A concept for direct surface modification on self-standing films of cellulose nanofibrils (CNF) is demonstrated using an aminosilane group in cellulose compatible solvent (dimethyl acetamide, DMA). The chemically modified structure efficiently prevents the oxygen molecules from interacting with the nanocellulose film in the presence of water molecules. Oxygen permeability values lower than 1 mL mm m-2 day-1 atm-1 were achieved at extremely high levels of relative humidity (RH95%). The aminosilane reaction is compared to conventional hydrophobization reaction using hexamethyldisilazane. The differences with respect to interactions between cellulosic nanofibrils, water and oxygen molecules taking place with aminated and silylated CNF films correlated with the degree of surface substitution, surface hydrophilicity and permeability of the formed layer. The self-condensation reactions taking place on the film surface during aminosilane-mediated bonding were decisive for low oxygen permeability. Experimental evidence on the importance of interfacial processes that hinder the water-cellulose interactions while keeping film's low affinity towards oxygen is demonstrated.
Original languageEnglish
Pages (from-to)309-317
Number of pages9
JournalCarbohydrate Polymers
Volume174
DOIs
Publication statusPublished - 15 Oct 2017
MoE publication typeA1 Journal article-refereed

Fingerprint

Oxygen
Cellulose
Molecules
Water
Cellulose films
Condensation reactions
Hydrophilicity
Surface treatment
Atmospheric humidity
Substitution reactions

Keywords

  • Cellulose nanofibrils
  • CNF film
  • Surface functionalization
  • Aminosilane reaction
  • Oxygen permeability
  • Relative humidity

Cite this

Peresin, Mari Soledad ; Kammiovirta, Kari ; Heikkinen, Harri ; Johansson, Leena-Sisko ; Vartiainen, Jari ; Setälä, Harri ; Österberg, Monika ; Tammelin, Tekla. / Understanding the mechanisms of oxygen diffusion through surface functionalized nanocellulose films. In: Carbohydrate Polymers. 2017 ; Vol. 174. pp. 309-317.
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Understanding the mechanisms of oxygen diffusion through surface functionalized nanocellulose films. / Peresin, Mari Soledad; Kammiovirta, Kari; Heikkinen, Harri; Johansson, Leena-Sisko; Vartiainen, Jari; Setälä, Harri; Österberg, Monika; Tammelin, Tekla.

In: Carbohydrate Polymers, Vol. 174, 15.10.2017, p. 309-317.

Research output: Contribution to journalArticleScientificpeer-review

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AU - Kammiovirta, Kari

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AU - Vartiainen, Jari

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AU - Österberg, Monika

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