Unexpected thermal aging effect on brittle fracture and elemental segregation in modern dissimilar metal weld

Andrea Fazi, Pedro A. Ferreirós, Yanling Ge, Song Lu, Mattias Thuvander, Zaiqing Que*

*Corresponding author for this work

Research output: Contribution to journalArticleScientificpeer-review

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Abstract

A full-scale dissimilar metal weld safe-end mock-up, precisely replicating a critical component of a modern nuclear power plant, was investigated. The brittle fracture behavior, carbide evolution and nanoscale elemental segregation in the heat-affected zone (HAZ) of low alloy steel (LAS) were analyzed under both post-weld heat-treated and thermally-aged conditions (400 °C for 15,000 h, equivalent to 90 years of operation) using analytical electron microscopy and atom probe tomography. The observed increase in grain boundary (GB) decohesion and intergranular cracking on the fracture surface and the decrease of fracture toughness are primarily attributed to P and Mn segregation to GBs and the coarsening of carbides upon long-term thermal aging. The direct observations of significant elemental segregation to GBs and the consequent reduction in fracture toughness in the HAZ are unexpected for modern low-phosphorus LASs, highlighting potential concerns for evaluating the structural integrity of modern nuclear power plants.
Original languageEnglish
Article number114419
JournalMaterials Characterization
Volume217
DOIs
Publication statusPublished - Nov 2024
MoE publication typeA1 Journal article-refereed

Funding

The authors wish to express their gratitude for the funding and support from Ringhals AB, OKG AB, Teollisuuden Voima Oyj and VTT Technical Research Centre of Finland within the FEMMA+ (Forum for the Effect of Thermal Aging and Microstructure on Mechanical and EAC Behavior of Ni-based Alloy Dissimilar Metal Welds+) research project. The authors also thank NKS for funding the NKS-FEMMA (AFT/NKS-R(24)134/2) project.

Keywords

  • Carbide
  • Dissimilar metal weld
  • Fracture
  • Segregation
  • Thermal aging

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