Utilization of steel, pulp and paper industry solid residues in forest soil amendment: Relevant physicochemical properties and heavy metal availability

Industrial residue application to soil was investigated by integrating granulated blast furnace or converter steel slag with residues from the pulp and paper industry in various formulations. Specimen analysis included relevant physicochemical properties, total element concentrations (HCl+HNO₃ digestion, USEPA 3051) and chemical speciation of chosen heavy metals (CH₃COOH, NH₂OH·HCl and H₂O₂+H₂O₂+CH₃COONH₄, the BCR method). Produced matrices showed liming effects comparable to commercial ground limestone and included significant quantities of soluble vital nutrients. The use of converter steel slag, however, led to significant increases in the total concentrations of Cr and V. Subsequently, total Cr was attested to occur as Cr(III) by Na₂CO₃+NaOH digestion followed by IC UV/VIS-PCR (USEPA 3060A). Additionally, 80.6% of the total concentration of Cr (370mgkg^-1, d.w.) occurred in the residual fraction. However, 46.0% of the total concentration of V (2470mgkg ^-1, d.w.) occurred in the easily reduced fraction indicating potential bioavailability.