Valorisation of baryte tailings for radiation shielding in plastics and nuclear waste disposal

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Abstract

Baryte (BaSO4) is a critical raw material with no functional recycling since the used applications are dissipative. Significant quantities of baryte end up in tailings as a side stream from the mining industry. Baryte from a secondary raw material source was used as a filler in plastics for low duty radiation shielding and as an aggregate in radiation shielding geopolymers needed for safely storing low-radioactive waste ash. Mechanical strength in geopolymers remained at a high level with 0–50 % baryte additions. Low-cost plastic composites with baryte additions showed promising attenuation for X-rays and gamma-rays. The results showed improved qualities in the direct use of the secondary baryte material in concrete and plastics in comparison to primary baryte. Baryte from an industrial waste stream was shown to be applicable to be used in radiation shielding in geopolymers for storing low-radioactive waste, and in plastics. Primary baryte can be replaced with secondary baryte to bring environmental, economic, and even functional benefits.
Original languageEnglish
Article numbere25719
JournalHeliyon
Volume10
Issue number3
DOIs
Publication statusPublished - 15 Feb 2024
MoE publication typeA1 Journal article-refereed

Funding

The work was funded by VTT Technical Research Centre of Finland Ltd. The authors thank Tapio Vehmas for mechanical strength measurements of geopolymers and Merja Tanhua-Tyrkkö for conducting radiation absorption measurements.

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 8 - Decent Work and Economic Growth
    SDG 8 Decent Work and Economic Growth
  2. SDG 9 - Industry, Innovation, and Infrastructure
    SDG 9 Industry, Innovation, and Infrastructure
  3. SDG 12 - Responsible Consumption and Production
    SDG 12 Responsible Consumption and Production

Keywords

  • Circular economy
  • Secondary material
  • Waste valorisation
  • Radiation shielding
  • Baryte
  • Tailings

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