XPS and the medium-dependent surface adaptation of cellulose in wood

Leena-Sisko Johansson (Corresponding Author), J.M. Campbell, Tuomas Hänninen, Christelle Ganne-Chédeville, Tapani Vuorinen, Mark Hughes, Janne Laine

    Research output: Contribution to journalArticleScientificpeer-review

    12 Citations (Scopus)

    Abstract

    We report reproducible XPS experiments on wood in two case studies. In the study on natural wood aging, we compared XPS bulk wood compositions of ancient and modern materials, analyzing spruce wood used as structural elements in roofs. Freshly cut specimens were analyzed before and after acetone extraction. In the other study, on wood surface aging, we used recently harvested, frozen pine as the sample material. In this experiment, never‐dried wood surfaces were exposed to dry conditions via different routes. Combining the data presented here with our earlier studies on paper and a recent solvent‐exchange study on nanofibrillated celluloses, we propose that both the lack of aging in the bulk wood and the rapid aging of the exposed wood surfaces are driven by the same process, i.e. the medium‐dependent surface adaptation of nature‐derived celluloses. Controlling this adaptation process is of a crucial importance in many technological applications of cellulose and wood materials.
    Original languageEnglish
    Pages (from-to)899-903
    Number of pages5
    JournalSurface and Interface Analysis
    Volume44
    Issue number8
    DOIs
    Publication statusPublished - 2012
    MoE publication typeA1 Journal article-refereed
    Event14th European Conference on Applications of Surface and Interface Analysis, ECASIA '11 - Cardiff, United Kingdom
    Duration: 4 Sep 20119 Sep 2011

    Fingerprint

    cellulose
    Cellulose
    Wood
    X ray photoelectron spectroscopy
    Aging of materials
    roofs
    Acetone
    Roofs
    acetone
    Experiments
    routes
    Chemical analysis

    Keywords

    • XPS
    • wood
    • cellulose
    • acetone extraction
    • surface adaptation

    Cite this

    Johansson, L-S., Campbell, J. M., Hänninen, T., Ganne-Chédeville, C., Vuorinen, T., Hughes, M., & Laine, J. (2012). XPS and the medium-dependent surface adaptation of cellulose in wood. Surface and Interface Analysis, 44(8), 899-903. https://doi.org/10.1002/sia.4839
    Johansson, Leena-Sisko ; Campbell, J.M. ; Hänninen, Tuomas ; Ganne-Chédeville, Christelle ; Vuorinen, Tapani ; Hughes, Mark ; Laine, Janne. / XPS and the medium-dependent surface adaptation of cellulose in wood. In: Surface and Interface Analysis. 2012 ; Vol. 44, No. 8. pp. 899-903.
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    abstract = "We report reproducible XPS experiments on wood in two case studies. In the study on natural wood aging, we compared XPS bulk wood compositions of ancient and modern materials, analyzing spruce wood used as structural elements in roofs. Freshly cut specimens were analyzed before and after acetone extraction. In the other study, on wood surface aging, we used recently harvested, frozen pine as the sample material. In this experiment, never‐dried wood surfaces were exposed to dry conditions via different routes. Combining the data presented here with our earlier studies on paper and a recent solvent‐exchange study on nanofibrillated celluloses, we propose that both the lack of aging in the bulk wood and the rapid aging of the exposed wood surfaces are driven by the same process, i.e. the medium‐dependent surface adaptation of nature‐derived celluloses. Controlling this adaptation process is of a crucial importance in many technological applications of cellulose and wood materials.",
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    Johansson, L-S, Campbell, JM, Hänninen, T, Ganne-Chédeville, C, Vuorinen, T, Hughes, M & Laine, J 2012, 'XPS and the medium-dependent surface adaptation of cellulose in wood', Surface and Interface Analysis, vol. 44, no. 8, pp. 899-903. https://doi.org/10.1002/sia.4839

    XPS and the medium-dependent surface adaptation of cellulose in wood. / Johansson, Leena-Sisko (Corresponding Author); Campbell, J.M.; Hänninen, Tuomas; Ganne-Chédeville, Christelle; Vuorinen, Tapani; Hughes, Mark; Laine, Janne.

    In: Surface and Interface Analysis, Vol. 44, No. 8, 2012, p. 899-903.

    Research output: Contribution to journalArticleScientificpeer-review

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    AU - Johansson, Leena-Sisko

    AU - Campbell, J.M.

    AU - Hänninen, Tuomas

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    AU - Vuorinen, Tapani

    AU - Hughes, Mark

    AU - Laine, Janne

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    AB - We report reproducible XPS experiments on wood in two case studies. In the study on natural wood aging, we compared XPS bulk wood compositions of ancient and modern materials, analyzing spruce wood used as structural elements in roofs. Freshly cut specimens were analyzed before and after acetone extraction. In the other study, on wood surface aging, we used recently harvested, frozen pine as the sample material. In this experiment, never‐dried wood surfaces were exposed to dry conditions via different routes. Combining the data presented here with our earlier studies on paper and a recent solvent‐exchange study on nanofibrillated celluloses, we propose that both the lack of aging in the bulk wood and the rapid aging of the exposed wood surfaces are driven by the same process, i.e. the medium‐dependent surface adaptation of nature‐derived celluloses. Controlling this adaptation process is of a crucial importance in many technological applications of cellulose and wood materials.

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    Johansson L-S, Campbell JM, Hänninen T, Ganne-Chédeville C, Vuorinen T, Hughes M et al. XPS and the medium-dependent surface adaptation of cellulose in wood. Surface and Interface Analysis. 2012;44(8):899-903. https://doi.org/10.1002/sia.4839